2-(2,5-dihydroxy-phenylsulfanyl)-2-furan-2-yl-1-(4-triisopropylsilanyloxy-phenyl)-ethanone

Base Information

Chemical Name:2-(2,5-dihydroxy-phenylsulfanyl)-2-furan-2-yl-1-(4-triisopropylsilanyloxy-phenyl)-ethanone
CAS No.:503444-99-3
Molecular Formula:C₂₇H₃₄O₅SSi
Molecular Weight:498.715
Hs Code.:

Synonyms:2-(2,5-dihydroxy-phenylsulfanyl)-2-furan-2-yl-1-(4-triisopropylsilanyloxy-phenyl)-ethanone

Suppliers and Price of 2-(2,5-dihydroxy-phenylsulfanyl)-2-furan-2-yl-1-(4-triisopropylsilanyloxy-phenyl)-ethanone

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of 2-(2,5-dihydroxy-phenylsulfanyl)-2-furan-2-yl-1-(4-triisopropylsilanyloxy-phenyl)-ethanone

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of 2-(2,5-dihydroxy-phenylsulfanyl)-2-furan-2-yl-1-(4-triisopropylsilanyloxy-phenyl)-ethanone

There total 5 articles about 2-(2,5-dihydroxy-phenylsulfanyl)-2-furan-2-yl-1-(4-triisopropylsilanyloxy-phenyl)-ethanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 2889-61-4
2-mercaptobenzene-1,4-diol

: 719311-13-4
2-bromo-2-furan-2-yl-1-(4-triisopropylsilanyloxy-phenyl)-ethanone

: 503444-99-3
2-(2,5-dihydroxy-phenylsulfanyl)-2-furan-2-yl-1-(4-triisopropylsilanyloxy-phenyl)-ethanone

Guidance literature:: With N-ethyl-N,N-diisopropylamine; In N,N-dimethyl-formamide; at 0 ℃;
DOI:10.1016/j.bmcl.2004.02.084

Reference yield:

: 55001-14-4
2-Furan-2-yl-1-(4-methoxy-phenyl)-ethanone

: 503444-99-3
2-(2,5-dihydroxy-phenylsulfanyl)-2-furan-2-yl-1-(4-triisopropylsilanyloxy-phenyl)-ethanone

Guidance literature:: Multi-step reaction with 4 steps

1: pyridine-HCl / 190 °C

2: NaH / tetrahydrofuran / 0 °C

3: 100 percent / PhN⁺Me₃Br₃^- / tetrahydrofuran / 0 °C

4: Hunig's base / dimethylformamide / 0 °C

With pyridine hydrochloride; phenyltrimethylammonium tribromide; sodium hydride; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; N,N-dimethyl-formamide;
DOI:10.1016/j.bmcl.2004.02.084

Reference yield:

: 719311-02-1
2-furan-2-yl-3-(4-methoxy-phenyl)-3-oxo-propionic acid ethyl ester

: 503444-99-3
2-(2,5-dihydroxy-phenylsulfanyl)-2-furan-2-yl-1-(4-triisopropylsilanyloxy-phenyl)-ethanone

Guidance literature:: Multi-step reaction with 5 steps

1: 82 percent / LiCl; aq. AcOH / 1-methyl-pyrrolidin-2-one / 130 °C

2: pyridine-HCl / 190 °C

3: NaH / tetrahydrofuran / 0 °C

4: 100 percent / PhN⁺Me₃Br₃^- / tetrahydrofuran / 0 °C

5: Hunig's base / dimethylformamide / 0 °C

With pyridine hydrochloride; phenyltrimethylammonium tribromide; sodium hydride; acetic acid; N-ethyl-N,N-diisopropylamine; lithium chloride; In tetrahydrofuran; 1-methyl-pyrrolidin-2-one; N,N-dimethyl-formamide;
DOI:10.1016/j.bmcl.2004.02.084