cyclohexyl(imino)(phenyl)-λ⁶-sulfanone

Base Information

• Chemical Name: cyclohexyl(imino)(phenyl)-λ⁶-sulfanone
• CAS No.: 71098-82-3
• Molecular Formula: C₁₂H₁₇NOS
• Molecular Weight: 223.339
• Mol file: 71098-82-3.mol

Synonyms:cyclohexyl(imino)(phenyl)-λ⁶-sulfanone

Chemical Property of cyclohexyl(imino)(phenyl)-λ⁶-sulfanone

Chemical Property:

Purity/Quality:

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Technology Process of cyclohexyl(imino)(phenyl)-λ⁶-sulfanone

There total 1 articles about cyclohexyl(imino)(phenyl)-λ⁶-sulfanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

cyclohexyl phenyl sulphide (7570-92-5) → cyclohexyl(imino)(phenyl)-λ6-sulfanone (71098-82-3)

Guidance literature:

With [bis(acetoxy)iodo]benzene; ammonium carbamate; In methanol; at 20 ℃;

DOI:10.1002/anie.201904543

Reference yield: 89.0%

2-(phenyl-λ3-iodaneylidene)cyclohexane-1,3-dione (86396-02-3) + cyclohexyl(imino)(phenyl)-λ6-sulfanone (71098-82-3) → 5-cyclopropyl-8,9-dihydro-5λ4-dibenzo[c,e][1,2]thiazin-10(7H)-one 5-oxide

Guidance literature:

With tris(acetonitrile)(η5-pentamethylcyclopentadienyl)rhodium(III) hexafluoroantimonate; In 2,2,2-trifluoroethanol; at 50 ℃; for 8h;

Reference yield: 80.0%

ethyl 2-diazo-3-oxobutanoate (2009-97-4) + cyclohexyl(imino)(phenyl)-λ6-sulfanone (71098-82-3) → C18H23NO3S

Guidance literature:

With silver hexafluoroantimonate; bis[dichloro(pentamethylcyclopentadienyl)ruthenium(III)]; 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate; at 30 ℃; for 24h;

upstream raw materials:

cyclohexyl phenyl sulphide

Downstream raw materials:

N-methyl cyclohexylphenyl sulfoximine

Refernces

• 1、 Chen, Lu,Hao, Liqiang,Ji, Yafei,Wang, Yangyang,Wang, Zhichao,Wu, Gaorong,Xu, Xiaobo. "Rhodium(iii)-catalyzed cascade C-H functionalization/annulation of sulfoximines with iodonium ylides for the synthesis of cyclohexanone-1,2-benzothiazines". supporting information. p. 887 - 894. Retrieved 2022/02/03.