(E)-4,5-di-O-acetyl-1,2-didehydro-1,2,6-trideoxy-3-O-methyl-1-(phenylthio)-L-arabino-hexose

Base Information

Chemical Name:(E)-4,5-di-O-acetyl-1,2-didehydro-1,2,6-trideoxy-3-O-methyl-1-(phenylthio)-L-arabino-hexose
CAS No.:123518-23-0
Molecular Formula:C₁₇H₂₂O₅S
Molecular Weight:338.425
Hs Code.:

Synonyms:(E)-4,5-di-O-acetyl-1,2-didehydro-1,2,6-trideoxy-3-O-methyl-1-(phenylthio)-L-arabino-hexose

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (E)-4,5-di-O-acetyl-1,2-didehydro-1,2,6-trideoxy-3-O-methyl-1-(phenylthio)-L-arabino-hexose

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of (E)-4,5-di-O-acetyl-1,2-didehydro-1,2,6-trideoxy-3-O-methyl-1-(phenylthio)-L-arabino-hexose

There total 1 articles about (E)-4,5-di-O-acetyl-1,2-didehydro-1,2,6-trideoxy-3-O-methyl-1-(phenylthio)-L-arabino-hexose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 13884-92-9
phenylthiomethyl triphenylphosphonium chloride

: 123518-22-9
3,4-di-O-acetyl-5-deoxy-2-O-methyl-aldehydo-L-arabinose

: 123518-27-4
(Z)-4,5-di-O-acetyl-1,2-didehydro-1,2,6-trideoxy-3-O-methyl-1-(phenylthio)-L-arabino-hexose

: 123518-23-0
(E)-4,5-di-O-acetyl-1,2-didehydro-1,2,6-trideoxy-3-O-methyl-1-(phenylthio)-L-arabino-hexose

: 791-28-6
Triphenylphosphine oxide

Guidance literature:: With sodium hydride; In dimethyl sulfoxide; Yield given. Yields of byproduct given. Title compound not separated from byproducts; 1.) a.) 75 deg C, 1 h; b.) 27 deg C, 1 h; 2.) RT;
DOI:10.1016/0008-6215(89)84090-X

Reference yield: 79.0%

: 123518-23-0,123518-27-4
4,5-di-O-acetyl-1,2-didehydro-1,2,6-trideoxy-3-O-methyl-1-(phenylthio)-L-arabino-hexose

: 123518-24-1,123518-28-5
1,2,6-trideoxy-1,2-didehydro-3-O-methyl-1-(phenylthio)-L-arabino-hexose

Guidance literature:: With ammonia; In methanol; for 20h; Ambient temperature;
DOI:10.1016/0008-6215(89)84090-X

Reference yield:

: 123518-23-0,123518-27-4
4,5-di-O-acetyl-1,2-didehydro-1,2,6-trideoxy-3-O-methyl-1-(phenylthio)-L-arabino-hexose

: 123518-25-2
C₂₁H₂₂O₆

Guidance literature:: Multi-step reaction with 3 steps

1: 79 percent / NH₃ / methanol / 20 h / Ambient temperature

2: mercuric oxide, mercuric chloride / H₂O; acetone / 3 h / 50 °C

3: 33 percent / pyridine / 18 h / Ambient temperature

With pyridine; ammonia; mercury dichloride; mercury(II) oxide; In methanol; water; acetone;
DOI:10.1016/0008-6215(89)84090-X