(S)-2-((1R,5R)-3-Benzyl-7-oxo-4-thia-2,6-diaza-bicyclo[3.2.0]hept-2-en-6-yl)-3,4-dichloro-3-chloromethyl-butyric acid benzyl ester

Base Information

Chemical Name:(S)-2-((1R,5R)-3-Benzyl-7-oxo-4-thia-2,6-diaza-bicyclo[3.2.0]hept-2-en-6-yl)-3,4-dichloro-3-chloromethyl-butyric acid benzyl ester
CAS No.:86832-62-4
Molecular Formula:C₂₃H₂₁Cl₃N₂O₃S
Molecular Weight:511.856
Hs Code.:

Synonyms:(S)-2-((1R,5R)-3-Benzyl-7-oxo-4-thia-2,6-diaza-bicyclo[3.2.0]hept-2-en-6-yl)-3,4-dichloro-3-chloromethyl-butyric acid benzyl ester

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Chemical Property of (S)-2-((1R,5R)-3-Benzyl-7-oxo-4-thia-2,6-diaza-bicyclo[3.2.0]hept-2-en-6-yl)-3,4-dichloro-3-chloromethyl-butyric acid benzyl ester

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Technology Process of (S)-2-((1R,5R)-3-Benzyl-7-oxo-4-thia-2,6-diaza-bicyclo[3.2.0]hept-2-en-6-yl)-3,4-dichloro-3-chloromethyl-butyric acid benzyl ester

There total 3 articles about (S)-2-((1R,5R)-3-Benzyl-7-oxo-4-thia-2,6-diaza-bicyclo[3.2.0]hept-2-en-6-yl)-3,4-dichloro-3-chloromethyl-butyric acid benzyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 86832-61-3
Benzyl 3-(Choromethyl)-3,4-dichloro-2-<3-(phenyldichloromethyl)-7-oxo-4-thia-2,6-diazabicyclo<3.2.0>hept-2-en-6-yl>butanoate

: 86832-62-4
(S)-2-((1R,5R)-3-Benzyl-7-oxo-4-thia-2,6-diaza-bicyclo[3.2.0]hept-2-en-6-yl)-3,4-dichloro-3-chloromethyl-butyric acid benzyl ester

Guidance literature:: With acetic acid; zinc; In dichloromethane; at 0 ℃; for 0.5h;
DOI:10.1021/jo00168a036

Reference yield:

: 86832-59-9
(R)-2-((1R,5R)-3-Benzyl-7-oxo-4-thia-2,6-diaza-bicyclo[3.2.0]hept-2-en-6-yl)-3-methyl-but-3-enoic acid benzyl ester

: 86832-62-4
(S)-2-((1R,5R)-3-Benzyl-7-oxo-4-thia-2,6-diaza-bicyclo[3.2.0]hept-2-en-6-yl)-3,4-dichloro-3-chloromethyl-butyric acid benzyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 50 percent / NaCl, conc. H₂SO₄ / CHCl₃; H₂O / Ambient temperature; 1) electrolysis, Pt electrodes, undivided cell, 10 mA/cm², 15 F/mol, 2) electrolysis 5 F/mol, irradiation

2: 96 percent / Zn powder, AcOH / CH₂Cl₂ / 0.5 h / 0 °C

With sulfuric acid; acetic acid; sodium chloride; zinc; In dichloromethane; chloroform; water;
DOI:10.1021/jo00168a036

Reference yield:

: 86832-60-2
(R)-3-Chloromethyl-2-[(1R,5R)-3-(dichloro-phenyl-methyl)-7-oxo-4-thia-2,6-diaza-bicyclo[3.2.0]hept-2-en-6-yl]-but-3-enoic acid benzyl ester

: 86832-62-4
(S)-2-((1R,5R)-3-Benzyl-7-oxo-4-thia-2,6-diaza-bicyclo[3.2.0]hept-2-en-6-yl)-3,4-dichloro-3-chloromethyl-butyric acid benzyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 98 percent / Cl₂ / CH₂Cl₂; CCl₄ / 0.17 h / Ambient temperature; Irradiation

2: 96 percent / Zn powder, AcOH / CH₂Cl₂ / 0.5 h / 0 °C

With chlorine; acetic acid; zinc; In tetrachloromethane; dichloromethane;
DOI:10.1021/jo00168a036