(E)-2-Methyl-3-(4-tetradecyloxy-phenyl)-acrylic acid 2,2-dimethyl-[1,3]dioxolan-4-ylmethyl ester

Base Information

Chemical Name:(E)-2-Methyl-3-(4-tetradecyloxy-phenyl)-acrylic acid 2,2-dimethyl-[1,3]dioxolan-4-ylmethyl ester
CAS No.:929117-93-1
Molecular Formula:C₃₀H₄₈O₅
Molecular Weight:488.708
Hs Code.:

Synonyms:(E)-2-Methyl-3-(4-tetradecyloxy-phenyl)-acrylic acid 2,2-dimethyl-[1,3]dioxolan-4-ylmethyl ester

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Chemical Property of (E)-2-Methyl-3-(4-tetradecyloxy-phenyl)-acrylic acid 2,2-dimethyl-[1,3]dioxolan-4-ylmethyl ester

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Technology Process of (E)-2-Methyl-3-(4-tetradecyloxy-phenyl)-acrylic acid 2,2-dimethyl-[1,3]dioxolan-4-ylmethyl ester

There total 4 articles about (E)-2-Methyl-3-(4-tetradecyloxy-phenyl)-acrylic acid 2,2-dimethyl-[1,3]dioxolan-4-ylmethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 100-79-8,36543-79-0
(R,S)-2,2-dimethyl-1,3-dioxolane-4-methanol

: 220779-22-6
-3-(4-(tetradecyloxy)phenyl)-2-methylprop-2-enoic acid

: 929117-93-1
(E)-2-Methyl-3-(4-tetradecyloxy-phenyl)-acrylic acid 2,2-dimethyl-[1,3]dioxolan-4-ylmethyl ester

Guidance literature:: With dmap; di-tert-butyl dicarbonate; In tetrahydrofuran; at 50 ℃;
DOI:10.1248/cpb.54.1725

Reference yield:

: (E)-2-Methyl-3-(4-tetradecyloxy-phenyl)-acrylic acid methyl ester

: 929117-93-1
(E)-2-Methyl-3-(4-tetradecyloxy-phenyl)-acrylic acid 2,2-dimethyl-[1,3]dioxolan-4-ylmethyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: KOH / methanol / 2 h / 20 °C

2: 92 percent / DMAP; BOC₂O / tetrahydrofuran / 50 °C

With dmap; potassium hydroxide; di-tert-butyl dicarbonate; In tetrahydrofuran; methanol;
DOI:10.1248/cpb.54.1725

Reference yield:

: 59117-17-8
4-tetradecyloxybenzaldehyde

: 929117-93-1
(E)-2-Methyl-3-(4-tetradecyloxy-phenyl)-acrylic acid 2,2-dimethyl-[1,3]dioxolan-4-ylmethyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 73 percent / DABCO / dioxane; H₂O / 168 h / 20 °C

2: I₂; NaBH₄ / tetrahydrofuran / 20 °C

3: KOH / methanol / 2 h / 20 °C

4: 92 percent / DMAP; BOC₂O / tetrahydrofuran / 50 °C

With 1,4-diaza-bicyclo[2.2.2]octane; dmap; potassium hydroxide; sodium tetrahydroborate; di-tert-butyl dicarbonate; iodine; In tetrahydrofuran; 1,4-dioxane; methanol; water; 1: Baylis-Hillman reaction;
DOI:10.1248/cpb.54.1725