cyclohexyl 2,6-dideoxy-3-O-<2,6-dideoxy-3-O-(2,6-dideoxy-3-O-(diethylisopropylsilyl)-4-O-isobutyryl-3-C-methyl-α-L-arabino-hexopyranosyl)-β-D-arabino-hexopyranosyl>-β-D-arabino-hexopyrnoside

Base Information

Chemical Name:cyclohexyl 2,6-dideoxy-3-O-<2,6-dideoxy-3-O-(2,6-dideoxy-3-O-(diethylisopropylsilyl)-4-O-isobutyryl-3-C-methyl-α-L-arabino-hexopyranosyl)-β-D-arabino-hexopyranosyl>-β-D-arabino-hexopyrnoside
CAS No.:151929-71-4
Molecular Formula:C₃₆H₆₆O₁₁Si
Molecular Weight:702.999
Hs Code.:

cyclohexyl 2,6-dideoxy-3-O-<2,6-dideoxy-3-O-(2,6-dideoxy-3-O-(diethylisopropylsilyl)-4-O-isobutyryl-3-C-methyl-α-L-arabino-hexopyranosyl)-β-D-arabino-hexopyranosyl>-β-D-arabino-hexopyrnoside

Synonyms:cyclohexyl 2,6-dideoxy-3-O-<2,6-dideoxy-3-O-(2,6-dideoxy-3-O-(diethylisopropylsilyl)-4-O-isobutyryl-3-C-methyl-α-L-arabino-hexopyranosyl)-β-D-arabino-hexopyranosyl>-β-D-arabino-hexopyrnoside

Suppliers and Price of cyclohexyl 2,6-dideoxy-3-O-<2,6-dideoxy-3-O-(2,6-dideoxy-3-O-(diethylisopropylsilyl)-4-O-isobutyryl-3-C-methyl-α-L-arabino-hexopyranosyl)-β-D-arabino-hexopyranosyl>-β-D-arabino-hexopyrnoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of cyclohexyl 2,6-dideoxy-3-O-<2,6-dideoxy-3-O-(2,6-dideoxy-3-O-(diethylisopropylsilyl)-4-O-isobutyryl-3-C-methyl-α-L-arabino-hexopyranosyl)-β-D-arabino-hexopyranosyl>-β-D-arabino-hexopyrnoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of cyclohexyl 2,6-dideoxy-3-O-<2,6-dideoxy-3-O-(2,6-dideoxy-3-O-(diethylisopropylsilyl)-4-O-isobutyryl-3-C-methyl-α-L-arabino-hexopyranosyl)-β-D-arabino-hexopyranosyl>-β-D-arabino-hexopyrnoside

There total 18 articles about cyclohexyl 2,6-dideoxy-3-O-<2,6-dideoxy-3-O-(2,6-dideoxy-3-O-(diethylisopropylsilyl)-4-O-isobutyryl-3-C-methyl-α-L-arabino-hexopyranosyl)-β-D-arabino-hexopyranosyl>-β-D-arabino-hexopyrnoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 151957-73-2
cyclohexyl 2,6-anhydro-3-O-<2,6-anhydro-3-O-(2,6-anhydro-3-O-(diethylisopropylsilyl)-4-O-isobutyryl-3-C-methyl-2-thio-β-L-mannopyranosyl)-4-O-benzyl-2-thio-β-D-mannosyl>-4-O-benzyl-2-thio-β-D-mannopyranoside

: 151929-71-4
cyclohexyl 2,6-dideoxy-3-O-<2,6-dideoxy-3-O-(2,6-dideoxy-3-O-(diethylisopropylsilyl)-4-O-isobutyryl-3-C-methyl-α-L-arabino-hexopyranosyl)-β-D-arabino-hexopyranosyl>-β-D-arabino-hexopyrnoside

Guidance literature:: With hydrogen; nickel; In 1,4-dioxane; ethanol; at 50 ℃; for 24h;
DOI:10.1016/S0040-4039(00)73854-8

Reference yield:

: 151929-60-1
1,3-di-O-acetyl-2,6-anhydro-4-O-benzyl-2-thio-β-D-altropyranose

: 151929-71-4
cyclohexyl 2,6-dideoxy-3-O-<2,6-dideoxy-3-O-(2,6-dideoxy-3-O-(diethylisopropylsilyl)-4-O-isobutyryl-3-C-methyl-α-L-arabino-hexopyranosyl)-β-D-arabino-hexopyranosyl>-β-D-arabino-hexopyrnoside

Guidance literature:: Multi-step reaction with 6 steps

1: 89 percent / TMSOTf / CH₂Cl₂ / 1.5 h / -30 - 0 °C

2: 96 percent / lithium aluminum hydride / tetrahydrofuran / 1.5 h / 0 °C

3: 99 percent / Dess-Martin periodinane / CH₂Cl₂ / 1 h / 25 °C

4: 79 percent / diisobutylaluminum hydride / toluene / 1 h / -78 °C

5: 89 percent / 4A molecular sieves, N-bromosuccinimide / CH₂Cl₂ / 0.5 h / -30 - -20 °C

6: 76 percent / H₂ / Raney Ni (W₄) / ethanol; dioxane / 24 h / 50 °C

With N-Bromosuccinimide; lithium aluminium tetrahydride; trimethylsilyl trifluoromethanesulfonate; 4 A molecular sieve; hydrogen; diisobutylaluminium hydride; Dess-Martin periodane; Raney Ni (W₄); In tetrahydrofuran; 1,4-dioxane; ethanol; dichloromethane; toluene;
DOI:10.1021/ja00118a008

Reference yield:

: (1S,3S,4S,7R,8R)-7-Benzyloxy-3-methoxy-8-(tetrahydro-pyran-2-yloxy)-2-oxa-5-thia-bicyclo[2.2.2]octane

: 151929-71-4
cyclohexyl 2,6-dideoxy-3-O-<2,6-dideoxy-3-O-(2,6-dideoxy-3-O-(diethylisopropylsilyl)-4-O-isobutyryl-3-C-methyl-α-L-arabino-hexopyranosyl)-β-D-arabino-hexopyranosyl>-β-D-arabino-hexopyrnoside

Guidance literature:: Multi-step reaction with 7 steps

1: 70 percent / TMSOTf / 1 h / 0 °C

2: 89 percent / TMSOTf / CH₂Cl₂ / 1.5 h / -30 - 0 °C

3: 96 percent / lithium aluminum hydride / tetrahydrofuran / 1.5 h / 0 °C

4: 99 percent / Dess-Martin periodinane / CH₂Cl₂ / 1 h / 25 °C

5: 79 percent / diisobutylaluminum hydride / toluene / 1 h / -78 °C

6: 89 percent / 4A molecular sieves, N-bromosuccinimide / CH₂Cl₂ / 0.5 h / -30 - -20 °C

7: 76 percent / H₂ / Raney Ni (W₄) / ethanol; dioxane / 24 h / 50 °C

With N-Bromosuccinimide; lithium aluminium tetrahydride; trimethylsilyl trifluoromethanesulfonate; 4 A molecular sieve; hydrogen; diisobutylaluminium hydride; Dess-Martin periodane; Raney Ni (W₄); In tetrahydrofuran; 1,4-dioxane; ethanol; dichloromethane; toluene;
DOI:10.1021/ja00118a008