(4S,5S)-5-({[tert-butyl(diphenyl)silyl]oxy}methyl)-4-methyldihydrofuran-2(3H)-one

Base Information

Chemical Name:(4S,5S)-5-({[tert-butyl(diphenyl)silyl]oxy}methyl)-4-methyldihydrofuran-2(3H)-one
CAS No.:103233-14-3
Molecular Formula:C₂₂H₂₈O₃Si
Molecular Weight:368.548
Hs Code.:

Synonyms:(4S,5S)-5-({[tert-butyl(diphenyl)silyl]oxy}methyl)-4-methyldihydrofuran-2(3H)-one

Suppliers and Price of (4S,5S)-5-({[tert-butyl(diphenyl)silyl]oxy}methyl)-4-methyldihydrofuran-2(3H)-one

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (4S,5S)-5-({[tert-butyl(diphenyl)silyl]oxy}methyl)-4-methyldihydrofuran-2(3H)-one

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Technology Process of (4S,5S)-5-({[tert-butyl(diphenyl)silyl]oxy}methyl)-4-methyldihydrofuran-2(3H)-one

There total 31 articles about (4S,5S)-5-({[tert-butyl(diphenyl)silyl]oxy}methyl)-4-methyldihydrofuran-2(3H)-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 140710-22-1,140852-34-2,140923-88-2
2-(tert-butyldiphenylsiloxymethyl)-3-methylcyclobutanone

: 103233-14-3,106820-50-2,110098-09-4,140710-23-2,140710-24-3
dihydro-5-(tert-butyldiphenylsiloxymethyl)-4-methyl-2(3H)-furanone

Guidance literature:: With sodium dihydrogenphosphate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; for 12h; Ambient temperature;
DOI:10.1016/S0957-4166(00)80211-6

Reference yield: 94.0%

: 139190-57-1
Methyl (3S,4S)-5-tert-butyldiphenylsiloxy-4-methoxymethoxy-3-methylpentanoate

: 103233-14-3
(4S,5S)-5-({[tert-butyl(diphenyl)silyl]oxy}methyl)-4-methyldihydrofuran-2(3H)-one

Guidance literature:: With dimethylboron bromide; In dichloromethane; at -78 ℃; for 1h;
DOI:10.1055/s-1991-28396

Reference yield: 92.0%

: 917-54-4
methyllithium

: 99315-76-1
(5S)-5-(tert-butyldiphenylsiloxymethyl)-2(5H)-furanone

: 103233-14-3
(4S,5S)-5-({[tert-butyl(diphenyl)silyl]oxy}methyl)-4-methyldihydrofuran-2(3H)-one

Guidance literature:: methyllithium; With copper(l) iodide; In diethyl ether; at 0 ℃; Inert atmosphere;

(5S)-5-(tert-butyldiphenylsiloxymethyl)-2(5H)-furanone; In diethyl ether; for 1h; Inert atmosphere; Cooling;
DOI:10.1021/acs.orglett.0c03615