Pd₂Cl₂((C₆H₅)2PCH₂P(C₆H₅)2)2(NSO₂C₆H₅)

Base Information

• Chemical Name: Pd₂Cl₂((C₆H₅)2PCH₂P(C₆H₅)2)2(NSO₂C₆H₅)
• CAS No.: 221367-27-7
• Molecular Formula: C₅₆H₄₉Cl₂NO₂P₄Pd₂S
• Molecular Weight: 1207.72
• Mol file: 221367-27-7.mol

Synonyms:Pd₂Cl₂((C₆H₅)2PCH₂P(C₆H₅)2)2(NSO₂C₆H₅)

Chemical Property of Pd₂Cl₂((C₆H₅)2PCH₂P(C₆H₅)2)2(NSO₂C₆H₅)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of Pd₂Cl₂((C₆H₅)2PCH₂P(C₆H₅)2)2(NSO₂C₆H₅)

There total 3 articles about Pd₂Cl₂((C₆H₅)2PCH₂P(C₆H₅)2)2(NSO₂C₆H₅) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

phenylsulfonyl azide (938-10-3) + {PdCl(μ-dppm)}2 (64345-29-5) → Pd2Cl2((C6H5)2PCH2P(C6H5)2)2(NSO2C6H5) (221367-27-7)

Guidance literature:

In dichloromethane; byproducts: N2; at room temp. for ca. 2 h; evapn., pptn. with MeOH;

DOI:10.1039/a700942i

Reference yield: 75.0%

phenylsulfonyl azide (938-10-3) + Pd2Cl2(μ-bis(diphenylphosphino)methane)2 (64345-29-5) → Pd2Cl2((C6H5)2PCH2P(C6H5)2)2(NSO2C6H5) (221367-27-7)

Guidance literature:

In dichloromethane; byproducts: N2; ca. 20°C, 1-2 h; solvent redn., pptn. by addn. of MeOH, washing (MeOH and Et2O), redissoln. (CH2Cl2), pptn. with MeOH; elem. anal.;

Reference yield:

phenylsulfonyl azide (938-10-3) + [Pd2Cl2(μ-bis(diphenylphosphino)methane)2] (64345-29-5) → [Pd2Cl2(μ-bis(diphenylphosphino)methane)2(μ-NSO2C6H5)] (221367-27-7)

Guidance literature:

In dichloromethane; byproducts: N2; excess azide, 0-30°C; not isolated, reaction followed by UV/VIS spectroscopy; Kinetics;

DOI:10.1021/ic980937p

upstream raw materials:

phenylsulfonyl azide

Pd2Cl2(μ-bis(diphenylphosphino)methane)2

{PdCl(μ-dppm)}2

[Pd2Cl2(μ-bis(diphenylphosphino)methane)2]