(2S,3S,4R,5R,6S)-2-methoxy-6-methyl-3,4,5-tris(phenylmethoxy)oxane

Base Information

Chemical Name:(2S,3S,4R,5R,6S)-2-methoxy-6-methyl-3,4,5-tris(phenylmethoxy)oxane
CAS No.:74841-88-6
Molecular Formula:C₂₈H₃₂O₅
Molecular Weight:448.559
Hs Code.:
DSSTox Substance ID:DTXSID70428232
Nikkaji Number:J2.783.058G
Wikidata:Q82241035
Mol file:74841-88-6.mol

Synonyms:74841-88-6;Methyl 2,3,4-tri-O-benzyl-b-L-fucopyranoside;(2S,3S,4R,5R,6S)-2-methoxy-6-methyl-3,4,5-tris(phenylmethoxy)oxane;Methyl 2,3,4,-Tri-O-benzyl-beta-L-fucopyranoside;(2S,3S,4R,5R,6S)-3,4,5-Tris(benzyloxy)-2-methoxy-6-methyltetrahydro-2H-pyran;DTXSID70428232;67576-77-6 (racemic);QTDLREJYMFIJBR-QUYLDEAFSA-N;W-203715;Methyl 2,3,4,-Tri-O-benzyl- beta -L-fucopyranoside;Methyl 2-O,3-O,4-O-tribenzyl-beta-L-fucopyranoside;METHYL 2,3,4-TRI-O-BENZYL-BETA-L-FUCOPYRANOSIDE;Methyl 2,3,4-tri-O-benzyl-6-deoxy-beta-L-galactopyranoside

Suppliers and Price of (2S,3S,4R,5R,6S)-2-methoxy-6-methyl-3,4,5-tris(phenylmethoxy)oxane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
Methyl2,3,4,-Tri-O-benzyl-β-L-fucopyranoside
500mg
$ 120.00

Medical Isotopes, Inc.
Methyl2-3-4-tri-O-benzyl-β-L-fucopyranoside
5 g
$ 715.00

Biosynth Carbosynth
Methyl 2,3,4-tri-O-benzyl-b-L-fucopyranoside
2 g
$ 168.00

Biosynth Carbosynth
Methyl 2,3,4-tri-O-benzyl-b-L-fucopyranoside
1 g
$ 89.30

Biosynth Carbosynth
Methyl 2,3,4-tri-O-benzyl-b-L-fucopyranoside
5 g
$ 315.00

AK Scientific
Methyl2,3,4-tri-O-benzyl-b-L-fucopyranoside
2g
$ 276.00

Total 4 raw suppliers

Chemical Property of (2S,3S,4R,5R,6S)-2-methoxy-6-methyl-3,4,5-tris(phenylmethoxy)oxane

Chemical Property:

PSA：46.15000
LogP:5.13380
Solubility.:Chloroform, Dichlormethane, Ethyl Acetate
XLogP3:4.5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:10
Exact Mass:448.22497412
Heavy Atom Count:33
Complexity:524

Purity/Quality:

95% ^*data from raw suppliers

Methyl2,3,4,-Tri-O-benzyl-β-L-fucopyranoside ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1C(C(C(C(O1)OC)OCC2=CC=CC=C2)OCC3=CC=CC=C3)OCC4=CC=CC=C4
Isomeric SMILES:C[C@H]1[C@H]([C@H]([C@@H]([C@H](O1)OC)OCC2=CC=CC=C2)OCC3=CC=CC=C3)OCC4=CC=CC=C4
Uses Methyl 2,3,4,-Tri-O-benzyl-β-L-fucopyranoside (cas# 74841-88-6) is a compound useful in organic synthesis.

Technology Process of (2S,3S,4R,5R,6S)-2-methoxy-6-methyl-3,4,5-tris(phenylmethoxy)oxane

There total 7 articles about (2S,3S,4R,5R,6S)-2-methoxy-6-methyl-3,4,5-tris(phenylmethoxy)oxane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.7%

: 65518-53-8
methyl 2,3,4-tri-O-benzyl-6-O-tosyl-α-D-mannopyranoside

: 33639-74-6,59055-57-1,67576-77-6,73174-44-4,73174-45-5,74841-88-6,83916-89-6,99212-28-9,73174-55-7
methyl 2,3,4-tri-O-benzyl-α-D-rhamnopyranoside

Guidance literature:: With lithium aluminium tetrahydride; In diethyl ether; benzene; for 0.5h; Heating;

Reference yield:

: 291753-79-2
methyl 2,3,4-tri-O-benzyl-6-deoxy-6-iodo-α-D-manno-pyranoside

: 33639-74-6,59055-57-1,67576-77-6,73174-44-4,73174-45-5,74841-88-6,83916-89-6,99212-28-9,73174-55-7
methyl 2,3,4-tri-O-benzyl-α-D-rhamnopyranoside

Guidance literature:: methyl 2,3,4-tri-O-benzyl-6-deoxy-6-iodo-α-D-manno-pyranoside; With sodium tetrahydroborate; In dimethyl sulfoxide; at 100 ℃;

In dimethyl sulfoxide; acetone; for 1h; Reflux;
DOI:10.1039/c2cc17623h

Reference yield:

: 34212-64-1,641635-63-4
methyl 2,3,4-tri-O-benzyl-α-D-mannopyranoside

: 33639-74-6,59055-57-1,67576-77-6,73174-44-4,73174-45-5,74841-88-6,83916-89-6,99212-28-9,73174-55-7
methyl 2,3,4-tri-O-benzyl-α-D-rhamnopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 85 percent / pyridine / 1) 0 deg C, 1 h, 2) RT, 48 h

2: 96.7 percent / LiAlH₄ / benzene; diethyl ether / 0.5 h / Heating

With pyridine; lithium aluminium tetrahydride; In diethyl ether; benzene;