NiI(C₆H₅)((C₆H₁₁)2PCH₂CH₂P(C₆H₁₁)2)

Base Information

Chemical Name:NiI(C₆H₅)((C₆H₁₁)2PCH₂CH₂P(C₆H₁₁)2)
CAS No.:97921-12-5
Molecular Formula:C₃₂H₅₃INiP₂
Molecular Weight:685.315
Hs Code.:

NiI(C<sub>6</sub>H<sub>5</sub>)((C<sub>6</sub>H<sub>11</sub>)2PCH<sub>2</sub>CH<sub>2</sub>P(C<sub>6</sub>H<sub>11</sub>)2)

Synonyms:NiI(C₆H₅)((C₆H₁₁)2PCH₂CH₂P(C₆H₁₁)2)

Suppliers and Price of NiI(C₆H₅)((C₆H₁₁)2PCH₂CH₂P(C₆H₁₁)2)

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of NiI(C₆H₅)((C₆H₁₁)2PCH₂CH₂P(C₆H₁₁)2)

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Technology Process of NiI(C₆H₅)((C₆H₁₁)2PCH₂CH₂P(C₆H₁₁)2)

There total 4 articles about NiI(C₆H₅)((C₆H₁₁)2PCH₂CH₂P(C₆H₁₁)2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 91513-98-3
Ni(η(2)-C2H4)(1,2-bis(dicyclohexylphosphino)ethane)

: 97921-12-5
NiI(C₆H₅)((C₆H₁₁)2PCH₂CH₂P(C₆H₁₁)2)

Guidance literature:: With iodobenzene; In benzene; byproducts: ethylene; mixt. of Ni-complex and PhI in benzene was stirred under N2 and heated at 50°C for 0.5 h; hexane was added, ppt. was filtered off, washed with hexane, dried, dissolved in CH2Cl2, soln. was filtered, treated with MeOH, allowed to stand overnight at room temp., crystals were filtered off, dried in vacuo; elem. anal.;

Reference yield:

: 96555-88-3
[(1,2-bis(dicyclohexylphosphino)ethane)dichloronickel(II)]

: 97921-12-5
NiI(C₆H₅)((C₆H₁₁)2PCH₂CH₂P(C₆H₁₁)2)

Guidance literature:: Multi-step reaction with 2 steps

1: lithium / tetrahydrofuran

2: iodobenzene / benzene

With lithium; iodobenzene; In tetrahydrofuran; benzene;

Reference yield:

: 114907-51-6
[η²-benzyne][1,2-bis(dicyclohexylphosphino)ethane]nickel(0)

: 97921-12-5
NiI(C₆H₅)((C₆H₁₁)2PCH₂CH₂P(C₆H₁₁)2)

: 97921-14-7
NiI(C₆H₄CH₃)((C₆H₁₁)2PCH₂CH₂P(C₆H₁₁)2)

: 97921-19-2
(bis(1,2-dicyclohexylphosphino)ethane)nickel diiodide

Guidance literature:: With methyl iodide; In neat (no solvent); Ni-complex was dissolved in excess of pure MeI under N2, soln. kept for30 min at room temp., reaction was monitored by (1)H NMR spectroscopy; soln. was evapd. to dryness, residue dissolved in CDCl3 and analyzed by(1)H and (31)P NMR (ca. 95% of iodo o-tolyl complex, ca. 5% of iodo phenyl complex and trace of diiodide);