[Pt(C₆F₅)2(CO)2]

Base Information

• Chemical Name: [Pt(C₆F₅)2(CO)2]
• CAS No.: 102779-23-7
• Molecular Formula: C₁₄F₁₀O₂Pt
• Molecular Weight: 585.217
• Mol file: 102779-23-7.mol

Synonyms:[Pt(C₆F₅)2(CO)2]

Chemical Property of [Pt(C₆F₅)2(CO)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Pt(C₆F₅)2(CO)2]

There total 1 articles about [Pt(C₆F₅)2(CO)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

tetrabutylammonium trans-bis(pentafluorophenyl)(carbony)(Cl)platinum(II) + silver perchlorate → [Pt(C6F5)2(CO)2] (102779-23-7)

Guidance literature:

With CO; In tetrahydrofuran; byproducts: AgCl, [N((CH2)3CH3)4]ClO4; inert atmosphere; addn. of AgClO4 to soln. of Pt-complex, stirring (20min), evapn. to dryness, extn. (Et2O), filtration off of AgCl and NBu4ClO4, evapn. (vac.), dissoln. in CH2Cl2, bubbling CO (pptn.); elem. anal.;

DOI:10.1021/om00139a012

Reference yield: 95.0%

[Pt(C6F5)2(CO)2] (102779-23-7) + ethyltriphenylphosphonium bromide (1530-32-1) → [P(C6H5)3C2H5](1+)*[Pt(C6F5)2Br(CO)](1-)=[P(C6H5)3C2H5][Pt(C6F5)2Br(CO)] (102779-29-3)

Guidance literature:

In dichloromethane; byproducts: CO; inert atmosphere; addn. of PPh3EtBr to soln. of Pt-complex, stirring; evapn. to dryness, dissolving (CH2Cl2), slow diffusion of n-hexane (-30°C); elem. anal.;

DOI:10.1021/om00139a012

Reference yield: 92.0%

[Pt(C6F5)2(CO)2] (102779-23-7) + dimethyldiphenylphosphonium iodide (1017-88-5) → [P(C6H5)2(CH3)2](1+)*[Pt(C6F5)2I(CO)](1-)=[P(C6H5)2(CH3)2][Pt(C6F5)2I(CO)] (102725-44-0)

Guidance literature:

In dichloromethane; byproducts: CO; inert atmosphere; addn. of PPh2Me2I to soln. of Pt-complex, stirring; evapn. to dryness, dissolving (Et2O), slow diffusion of n-hexane (-30°C); elem. anal.;

DOI:10.1021/om00139a012

Downstream raw materials:

[Pt(C₆F₅)2(C₅H₅N)(CO)]

[P(C₆H₅)2(CH₃)2]⁽¹⁺⁾*[Pt(C₆F₅)2I(CO)]^(1-)=[P(C₆H₅)2(CH₃)2][Pt(C₆F₅)2I(CO)]

[P(C₆H₅)3C₂H₅]⁽¹⁺⁾*[Pt(C₆F₅)2Br(CO)]^(1-)=[P(C₆H₅)3C₂H₅][Pt(C₆F₅)2Br(CO)]

[P(C₆H₅)3C₂H₅]⁽¹⁺⁾*[Pt(C₆F₅)2Br(CO)]^(1-)=[P(C₆H₅)3C₂H₅][Pt(C₆F₅)2Br(CO)]