dicarbonyl(η-methylcyclopentadienyl)(triphenyl phosphite)manganese

Base Information

Chemical Name:dicarbonyl(η-methylcyclopentadienyl)(triphenyl phosphite)manganese
CAS No.:12100-96-8
Molecular Formula:C₂₆H₂₂MnO₅P
Molecular Weight:500.369
Hs Code.:

Synonyms:dicarbonyl(η-methylcyclopentadienyl)(triphenyl phosphite)manganese

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Chemical Property of dicarbonyl(η-methylcyclopentadienyl)(triphenyl phosphite)manganese

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Technology Process of dicarbonyl(η-methylcyclopentadienyl)(triphenyl phosphite)manganese

There total 2 articles about dicarbonyl(η-methylcyclopentadienyl)(triphenyl phosphite)manganese which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: 101-02-0
triphenyl phosphite

: methylcyclopentadienyl manganese(I) tricarbonyl

: 12100-96-8
dicarbonyl(η-methylcyclopentadienyl)(triphenyl phosphite)manganese

Guidance literature:: In hexane; Irradiation (UV/VIS); N2-atmosphere; slight excess of P(OPh)3, 250-W Hg lamp, 140 h; solvent removal, recrystn. (hot hexane); elem. anal.;
DOI:10.1039/DT9770000931

Reference yield:

: 101-02-0
triphenyl phosphite

: (methylcyclopentadienyl)(pyridine)dicarbonylmanganese

: 12100-96-8
dicarbonyl(η-methylcyclopentadienyl)(triphenyl phosphite)manganese

Guidance literature:: With tetraethylammonium perchlorate; In acetone; byproducts: pyridine; Electrolysis; at 22 °C under N2, supporting electrolyte: 0.1 N TEAP; the strirred soln. of the complex compd. was reduced at -0.5 V for several min, the new ligand was added and stirred for 1 h at room temp., then oxidized at 1000 μA; the anolyte was diluted with deoxygenated water, the ppt. was isolated by filtration;
DOI:10.1021/ja00339a012

Reference yield: 57.0%

: 12100-96-8
dicarbonyl(η-methylcyclopentadienyl)(triphenyl phosphite)manganese

: 69036-00-6
1-chloro-2,2-diphenyl-1-(trimethylsilyl)ethene

: 119747-57-8
CH₃C₅H₄Mn(CO)P(OC₆H₅)3CC(C₆H₅)2

Guidance literature:: In toluene; byproducts: CO, (CH3)3SiCl; Irradiation (UV/VIS); (N2); soln. of Mn complex and vinyl compd. was irradiated at -20°C for 10 h, filtered soln. was evpd. to dryness under high vac.; chromy. (silica gel, petroleum ether/toluene 10:1) at -20°C; elem. anal.;