(7S)-2,7-Anhydro-8,9,10,12,13-pentadeoxy-11-O-<(4-methoxyphenyl)methyl>-10-methylene-3,4-bis-C-<(phenylmethoxy)carbonyl>-12-(phenylmethyl)-L-erythro-L-glycero-D-altro-7-trideculo-7,4-furanosonic acid phenylmethyl ester

Base Information

Chemical Name:(7S)-2,7-Anhydro-8,9,10,12,13-pentadeoxy-11-O-<(4-methoxyphenyl)methyl>-10-methylene-3,4-bis-C-<(phenylmethoxy)carbonyl>-12-(phenylmethyl)-L-erythro-L-glycero-D-altro-7-trideculo-7,4-furanosonic acid phenylmethyl ester
CAS No.:162107-38-2
Molecular Formula:C₅₂H₅₄O₁₃
Molecular Weight:886.993
Hs Code.:

(7S)-2,7-Anhydro-8,9,10,12,13-pentadeoxy-11-O-<(4-methoxyphenyl)methyl>-10-methylene-3,4-bis-C-<(phenylmethoxy)carbonyl>-12-(phenylmethyl)-L-erythro-L-glycero-D-altro-7-trideculo-7,4-furanosonic acid phenylmethyl ester

Synonyms:(7S)-2,7-Anhydro-8,9,10,12,13-pentadeoxy-11-O-<(4-methoxyphenyl)methyl>-10-methylene-3,4-bis-C-<(phenylmethoxy)carbonyl>-12-(phenylmethyl)-L-erythro-L-glycero-D-altro-7-trideculo-7,4-furanosonic acid phenylmethyl ester

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Chemical Property of (7S)-2,7-Anhydro-8,9,10,12,13-pentadeoxy-11-O-<(4-methoxyphenyl)methyl>-10-methylene-3,4-bis-C-<(phenylmethoxy)carbonyl>-12-(phenylmethyl)-L-erythro-L-glycero-D-altro-7-trideculo-7,4-furanosonic acid phenylmethyl ester

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Technology Process of (7S)-2,7-Anhydro-8,9,10,12,13-pentadeoxy-11-O-<(4-methoxyphenyl)methyl>-10-methylene-3,4-bis-C-<(phenylmethoxy)carbonyl>-12-(phenylmethyl)-L-erythro-L-glycero-D-altro-7-trideculo-7,4-furanosonic acid phenylmethyl ester

There total 24 articles about (7S)-2,7-Anhydro-8,9,10,12,13-pentadeoxy-11-O-<(4-methoxyphenyl)methyl>-10-methylene-3,4-bis-C-<(phenylmethoxy)carbonyl>-12-(phenylmethyl)-L-erythro-L-glycero-D-altro-7-trideculo-7,4-furanosonic acid phenylmethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 21.0%

: 89238-99-3
O-(4-methoxybenzyl)-trichloroacetimidate

: 162107-37-1
(7S)-2,7-Anhydro-8,9,10,12,13-pentadeoxy-10-methylene-3,4-bis-C-<(phenylmethoxy)carbonyl>-12-(phenylmethyl)-L-erythro-L-glycero-D-altro-7-trideculo-7,4-furanosonic acid phenylmethyl ester

: 162107-38-2
(7S)-2,7-Anhydro-8,9,10,12,13-pentadeoxy-11-O-<(4-methoxyphenyl)methyl>-10-methylene-3,4-bis-C-<(phenylmethoxy)carbonyl>-12-(phenylmethyl)-L-erythro-L-glycero-D-altro-7-trideculo-7,4-furanosonic acid phenylmethyl ester

Guidance literature:: With camphor-10-sulfonic acid; In dichloromethane; at 25 ℃; for 0.75h;

Reference yield:

: 164118-30-3
<5(2E,4S,6S),7S>-2,7-Anhydro-8,9,10,12,13-pentadeoxy-11-O-<(4-methoxyphenyl)methyl>-10-methylene-3,4-bis-C-<(phenylmethoxy)carbonyl>-12-(phenylmethyl)-5-(4,6-dimethyl-2-octenoate)-L-erythro-L-glycero-D-altro-7-trideculo-7,4-furanosonic acid phenylmet...

: 162107-38-2
(7S)-2,7-Anhydro-8,9,10,12,13-pentadeoxy-11-O-<(4-methoxyphenyl)methyl>-10-methylene-3,4-bis-C-<(phenylmethoxy)carbonyl>-12-(phenylmethyl)-L-erythro-L-glycero-D-altro-7-trideculo-7,4-furanosonic acid phenylmethyl ester

Guidance literature:: Multi-step reaction with 10 steps

1: 79 percent / pyridine / CH₂Cl₂ / 0.17 h / 22 °C

2: 98 percent / DDQ / CH₂Cl₂; H₂O / 1 h / 22 °C

3: 99 percent / pyridine, DMAP / CH₂Cl₂ / 4 h / 22 °C

4: 85 percent / TBAF / tetrahydrofuran / 0.25 h / 0 °C

5: 50 percent / 10percent Pd/C / dioxane; various solvent(s) / 3 h / Heating

6: 99 percent / toluene / 2 h / Heating

7: 51 percent / 3percent HCl / methanol / 2 h / 22 °C

8: 68 percent / CSA / CH₂Cl₂; cyclohexane / 12 h / 22 °C

9: LiOH*H₂O / tetrahydrofuran; H₂O / 12 h / 22 °C

10: toluene / 2 h / Heating

With pyridine; hydrogenchloride; dmap; lithium hydroxide; camphor-10-sulfonic acid; tetrabutyl ammonium fluoride; 2,3-dicyano-5,6-dichloro-p-benzoquinone; palladium on activated charcoal; In tetrahydrofuran; 1,4-dioxane; methanol; dichloromethane; cyclohexane; water; toluene;

Reference yield:

: 164118-33-6
<5(2E,4S,6S),7S>-2,7-Anhydro-8,9,10,12,13-pentadeoxy-11-O-<(4-methoxyphenyl)methyl>-10-methylene-3,4-bis-C-<(phenylmethoxy)carbonyl>-12-(phenylmethyl)-6-O-(triethylsilyl)-5-(4,6-dimethyl-2-octenoate)-L-erythro-L-glycero-D-altro-7-trideculo-7,4-furano...

: 162107-38-2
(7S)-2,7-Anhydro-8,9,10,12,13-pentadeoxy-11-O-<(4-methoxyphenyl)methyl>-10-methylene-3,4-bis-C-<(phenylmethoxy)carbonyl>-12-(phenylmethyl)-L-erythro-L-glycero-D-altro-7-trideculo-7,4-furanosonic acid phenylmethyl ester

Guidance literature:: Multi-step reaction with 9 steps

1: 98 percent / DDQ / CH₂Cl₂; H₂O / 1 h / 22 °C

2: 99 percent / pyridine, DMAP / CH₂Cl₂ / 4 h / 22 °C

3: 85 percent / TBAF / tetrahydrofuran / 0.25 h / 0 °C

4: 50 percent / 10percent Pd/C / dioxane; various solvent(s) / 3 h / Heating

5: 99 percent / toluene / 2 h / Heating

6: 51 percent / 3percent HCl / methanol / 2 h / 22 °C

7: 68 percent / CSA / CH₂Cl₂; cyclohexane / 12 h / 22 °C

8: LiOH*H₂O / tetrahydrofuran; H₂O / 12 h / 22 °C

9: toluene / 2 h / Heating

With pyridine; hydrogenchloride; dmap; lithium hydroxide; camphor-10-sulfonic acid; tetrabutyl ammonium fluoride; 2,3-dicyano-5,6-dichloro-p-benzoquinone; palladium on activated charcoal; In tetrahydrofuran; 1,4-dioxane; methanol; dichloromethane; cyclohexane; water; toluene;