tri-tert-butyl (((((benzene-1,3,5-triyltris(methylene))tris-(azanediyl))tris(butane-4,1-diyl))tris((tert-butoxycarbonyl)-azanediyl))tris(butane-4,1-diyl))tris(methylcarbamate)

Base Information

• Chemical Name: tri-tert-butyl (((((benzene-1,3,5-triyltris(methylene))tris-(azanediyl))tris(butane-4,1-diyl))tris((tert-butoxycarbonyl)-azanediyl))tris(butane-4,1-diyl))tris(methylcarbamate)
• CAS No.: 1533410-87-5
• Molecular Formula: C₆₆H₁₂₃N₉O₁₂
• Molecular Weight: 1234.76
• Mol file: 1533410-87-5.mol

Synonyms:tri-tert-butyl (((((benzene-1,3,5-triyltris(methylene))tris-(azanediyl))tris(butane-4,1-diyl))tris((tert-butoxycarbonyl)-azanediyl))tris(butane-4,1-diyl))tris(methylcarbamate)

Chemical Property of tri-tert-butyl (((((benzene-1,3,5-triyltris(methylene))tris-(azanediyl))tris(butane-4,1-diyl))tris((tert-butoxycarbonyl)-azanediyl))tris(butane-4,1-diyl))tris(methylcarbamate)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tri-tert-butyl (((((benzene-1,3,5-triyltris(methylene))tris-(azanediyl))tris(butane-4,1-diyl))tris((tert-butoxycarbonyl)-azanediyl))tris(butane-4,1-diyl))tris(methylcarbamate)

There total 4 articles about tri-tert-butyl (((((benzene-1,3,5-triyltris(methylene))tris-(azanediyl))tris(butane-4,1-diyl))tris((tert-butoxycarbonyl)-azanediyl))tris(butane-4,1-diyl))tris(methylcarbamate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C66H117N9O12 → tri-tert-butyl (((((benzene-1,3,5-triyltris(methylene))tris-(azanediyl))tris(butane-4,1-diyl))tris((tert-butoxycarbonyl)-azanediyl))tris(butane-4,1-diyl))tris(methylcarbamate) (1533410-87-5)

Guidance literature:

With sodium tetrahydroborate; In methanol; dichloromethane; at 0 - 20 ℃; Inert atmosphere;

DOI:10.1021/jm401174a

Reference yield:

1,3,5-tris-(methoxycarbonyl)benzene (2672-58-4) → tri-tert-butyl (((((benzene-1,3,5-triyltris(methylene))tris-(azanediyl))tris(butane-4,1-diyl))tris((tert-butoxycarbonyl)-azanediyl))tris(butane-4,1-diyl))tris(methylcarbamate) (1533410-87-5)

Guidance literature:

Multi-step reaction with 4 steps

1: lithium aluminium tetrahydride / tetrahydrofuran / 14 h / 0 - 20 °C / Inert atmosphere

2: 2-iodoxybenzoic acid / tert-butyl alcohol / 2 h / 95 °C / Reflux; Inert atmosphere

3: methanol; dichloromethane / Inert atmosphere

4: sodium tetrahydroborate / methanol; dichloromethane / 0 - 20 °C / Inert atmosphere

With sodium tetrahydroborate; lithium aluminium tetrahydride; 2-iodoxybenzoic acid; In tetrahydrofuran; methanol; dichloromethane; tert-butyl alcohol;

DOI:10.1021/jm401174a

Reference yield:

benzene-1,3,5-trialdehyde (3163-76-6) → tri-tert-butyl (((((benzene-1,3,5-triyltris(methylene))tris-(azanediyl))tris(butane-4,1-diyl))tris((tert-butoxycarbonyl)-azanediyl))tris(butane-4,1-diyl))tris(methylcarbamate) (1533410-87-5)

Guidance literature:

Multi-step reaction with 2 steps

1: methanol; dichloromethane / Inert atmosphere

2: sodium tetrahydroborate / methanol; dichloromethane / 0 - 20 °C / Inert atmosphere

With sodium tetrahydroborate; In methanol; dichloromethane;

DOI:10.1021/jm401174a

upstream raw materials:

1,3,5-tris-(methoxycarbonyl)benzene

1,3,5-tris(hydroxymethyl)benzene

benzene-1,3,5-trialdehyde