3-(tert-butyl-diphenyl-silanyloxy)-5-[(E)-3-iodo-2-methylallyl]-phenylamine

Base Information

Chemical Name:3-(tert-butyl-diphenyl-silanyloxy)-5-[(E)-3-iodo-2-methylallyl]-phenylamine
CAS No.:936824-91-8
Molecular Formula:C₂₆H₃₀INOSi
Molecular Weight:527.52
Hs Code.:

Synonyms:3-(tert-butyl-diphenyl-silanyloxy)-5-[(E)-3-iodo-2-methylallyl]-phenylamine

Suppliers and Price of 3-(tert-butyl-diphenyl-silanyloxy)-5-[(E)-3-iodo-2-methylallyl]-phenylamine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 3-(tert-butyl-diphenyl-silanyloxy)-5-[(E)-3-iodo-2-methylallyl]-phenylamine

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 3-(tert-butyl-diphenyl-silanyloxy)-5-[(E)-3-iodo-2-methylallyl]-phenylamine

There total 2 articles about 3-(tert-butyl-diphenyl-silanyloxy)-5-[(E)-3-iodo-2-methylallyl]-phenylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 875439-71-7
3-[3-tert-butoxycarbonylamino-5-(tert-butyl-diphenyl-silanyloxy)-phenyl]-1-trimethylsilyl-propyne

: 936824-91-8
3-(tert-butyl-diphenyl-silanyloxy)-5-[(E)-3-iodo-2-methylallyl]-phenylamine

Guidance literature:: Multi-step reaction with 3 steps

1.1: 88 percent / tetra-n-butylammonium fluoride trihydrate / tetrahydrofuran / -20 - 0 °C

2.1: Cp₂ZrCl₂ / hexane; 1,2-dichloro-ethane / 0.83 h / 0 - 20 °C

2.2: 1,2-dichloro-ethane; hexane / 72 h / 20 °C

2.3: 58 percent / iodine / 1,2-dichloro-ethane; hexane; tetrahydrofuran / -30 - 0 °C

3.1: 94 percent / imidazole; DMAP / CH₂Cl₂ / 1.5 h

With 1H-imidazole; dmap; zirconocene dichloride; tetrabutyl ammonium fluoride; In tetrahydrofuran; hexane; dichloromethane; 1,2-dichloro-ethane;
DOI:10.1021/ol0702270

Reference yield:

: 875439-72-8
3-[3-tert-butoxycarbonylamino-5-hydroxy-phenyl]-1-propyne

: 936824-91-8
3-(tert-butyl-diphenyl-silanyloxy)-5-[(E)-3-iodo-2-methylallyl]-phenylamine

Guidance literature:: Multi-step reaction with 2 steps

1.1: Cp₂ZrCl₂ / hexane; 1,2-dichloro-ethane / 0.83 h / 0 - 20 °C

1.2: 1,2-dichloro-ethane; hexane / 72 h / 20 °C

1.3: 58 percent / iodine / 1,2-dichloro-ethane; hexane; tetrahydrofuran / -30 - 0 °C

2.1: 94 percent / imidazole; DMAP / CH₂Cl₂ / 1.5 h

With 1H-imidazole; dmap; zirconocene dichloride; In hexane; dichloromethane; 1,2-dichloro-ethane;
DOI:10.1021/ol0702270