5-(3,7-dimethylocta-2E,6-dienyl)-5-methoxycarbonylhex-2E-enedioic acid 1-benzyl ester 6-dimethyl ester

Base Information

Chemical Name:5-(3,7-dimethylocta-2E,6-dienyl)-5-methoxycarbonylhex-2E-enedioic acid 1-benzyl ester 6-dimethyl ester
CAS No.:852402-27-8
Molecular Formula:C₂₆H₃₄O₆
Molecular Weight:442.552
Hs Code.:

Synonyms:5-(3,7-dimethylocta-2E,6-dienyl)-5-methoxycarbonylhex-2E-enedioic acid 1-benzyl ester 6-dimethyl ester

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Chemical Property of 5-(3,7-dimethylocta-2E,6-dienyl)-5-methoxycarbonylhex-2E-enedioic acid 1-benzyl ester 6-dimethyl ester

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Technology Process of 5-(3,7-dimethylocta-2E,6-dienyl)-5-methoxycarbonylhex-2E-enedioic acid 1-benzyl ester 6-dimethyl ester

There total 1 articles about 5-(3,7-dimethylocta-2E,6-dienyl)-5-methoxycarbonylhex-2E-enedioic acid 1-benzyl ester 6-dimethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 72444-93-0
(4E,8E)-methyl 2-methoxycarbonyl-5,9-dimethyldeca-4,8-dienoate

: 852402-28-9
4-bromobut-2E-enoic acid benzyl ester

: 852402-27-8
5-(3,7-dimethylocta-2E,6-dienyl)-5-methoxycarbonylhex-2E-enedioic acid 1-benzyl ester 6-dimethyl ester

Guidance literature:: (4E,8E)-methyl 2-methoxycarbonyl-5,9-dimethyldeca-4,8-dienoate; With sodium hydride; In tetrahydrofuran; at 0 ℃;

4-bromobut-2E-enoic acid benzyl ester; In tetrahydrofuran; for 16h;
DOI:10.1021/ja042595u

Reference yield: 87.0%

: 852402-27-8
5-(3,7-dimethylocta-2E,6-dienyl)-5-methoxycarbonylhex-2E-enedioic acid 1-benzyl ester 6-dimethyl ester

: 852402-33-6
5-(6,7-dihydroxy-3,7-dimethyloct-2E-enyl)-5-methoxycarbonylhex-2E-enedioic acid 1-benzyl ester 6-methyl ester

Guidance literature:: With AD-mix-α; methanesulfonamide; In water; tert-butyl alcohol; at 0 ℃; for 14h;
DOI:10.1021/ja042595u

Reference yield:

: 852402-27-8
5-(3,7-dimethylocta-2E,6-dienyl)-5-methoxycarbonylhex-2E-enedioic acid 1-benzyl ester 6-dimethyl ester

: 852402-36-9
5-methoxycarbonyl-5-(3-methyl-6-oxohex-2E-enyl)hex-2E-enedioic acid 1-benzyl ester 6-methyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 87 percent / AD-Mix α(TM); CH3SO2NH2 / 2-methyl-propan-2-ol; H2O / 14 h / 0 °C

2: 89 percent / aq. NaIO₄ / tetrahydrofuran / 17 h

With sodium periodate; AD-mix-α; methanesulfonamide; In tetrahydrofuran; water; tert-butyl alcohol;
DOI:10.1021/ja042595u