2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO SILVER (I)

Base Information

Chemical Name:2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO SILVER (I)
CAS No.:79827-25-1
Molecular Formula:C₁₁H₁₉AgO₂
Molecular Weight:291.139
Hs Code.:
Mol file:79827-25-1.mol

Synonyms:Silver,(2,2,6,6-tetramethyl-3,5-heptanedionato-O,O')-; Silver,(2,2,6,6-tetramethyl-3,5-heptanedionato-kO,kO')- (9CI); 3,5-Heptanedione, 2,2,6,6-tetramethyl-, silver complex;(2,2,6,6-Tetramethyl-3,5-heptanedionato)silver

Suppliers and Price of 2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO SILVER (I)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Strem Chemicals
2,2,6,6-Tetramethyl-3,5-heptanedionato silver(I) (99.9%-Ag) [Ag(TMHD)]
5g
$ 237.00

Strem Chemicals
2,2,6,6-Tetramethyl-3,5-heptanedionato silver(I) (99.9%-Ag) [Ag(TMHD)]
1g
$ 63.00

Strem Chemicals
2,2,6,6-Tetramethyl-3,5-heptanedionato silver(I) (99.9%-Ag) [Ag(TMHD)]
25g
$ 947.00

American Custom Chemicals Corporation
2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO SILVER (I) 95.00%
5MG
$ 505.91

Total 14 raw suppliers

Chemical Property of 2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO SILVER (I)

Chemical Property:

Melting Point:178°C (dec.)
PSA：26.30000
LogP:3.01250

Purity/Quality:

99%, ^*data from raw suppliers

2,2,6,6-Tetramethyl-3,5-heptanedionato silver(I) (99.9%-Ag) [Ag(TMHD)] ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:
Statements: 36/37/38
Safety Statements: 26-36/37/39

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO SILVER (I)

There total 2 articles about 2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO SILVER (I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

: 1118-71-4
2,2,6,6-tetramethylheptane-3,5-dione

: silver nitrate

: 79827-25-1
(2,2,6,6-tetramethyl-3,5-heptanedionato)silver(I)

Guidance literature:: With triethylamine; In methanol; acetonitrile; (inert atm.), stirred slurry of AgNO3 in CH3CN/CH3OH cooled to 0°C, mixed with ligand and triethylamine in methanol, stirred at 0°C for 1 h; filtered, washed (methanol), dried (vac.), elem. anal.;
DOI:10.1016/S0277-5387(02)00980-4

Reference yield:

: 17574-99-1
sodium dipivaloylmethanate

: silver nitrate

: 79827-25-1
(2,2,6,6-tetramethyl-3,5-heptanedionato)silver(I)

Guidance literature:: In methanol; water; to AgNO3 in water was added a suspension of Na(thd) in methanol; light brown ppt. was sepd., soln. was stirred for 5 min, solid was collected by filtration and dried in vac. over P4O10 for 24 h;
DOI:10.1021/ja00366a003

Reference yield: 98.0%

: 79827-25-1
(2,2,6,6-tetramethyl-3,5-heptanedionato)silver(I)

: 420782-03-2,849590-85-8
[P(C₆H₄CH₂NMe₂-2)3]CuCl

: 680602-14-6
[(C₆H₄CH₂NMe₂-2)3PCu(I)(2,2,6,6-tetramethyl-3,5-heptanedionate)]

Guidance literature:: In tetrahydrofuran; byproducts: AgCl; all manipulations under N2 atm.; Cu compd. dissolved in THF, ligand added at 25°C, stirred for 3 h; filtered through kieselguhr, volatiles evapd. in vac., washed with petroleum ether; elem. anal.;