(R)-2-methyl-5-(3-(triisopropylsilyloxy)prop-1-en-2-yl)cyclohex-2-enone

Base Information

Chemical Name:(R)-2-methyl-5-(3-(triisopropylsilyloxy)prop-1-en-2-yl)cyclohex-2-enone
CAS No.:1404195-48-7
Molecular Formula:C₁₉H₃₄O₂Si
Molecular Weight:322.563
Hs Code.:

Synonyms:(R)-2-methyl-5-(3-(triisopropylsilyloxy)prop-1-en-2-yl)cyclohex-2-enone

Suppliers and Price of (R)-2-methyl-5-(3-(triisopropylsilyloxy)prop-1-en-2-yl)cyclohex-2-enone

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (R)-2-methyl-5-(3-(triisopropylsilyloxy)prop-1-en-2-yl)cyclohex-2-enone

Chemical Property:

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Technology Process of (R)-2-methyl-5-(3-(triisopropylsilyloxy)prop-1-en-2-yl)cyclohex-2-enone

There total 3 articles about (R)-2-methyl-5-(3-(triisopropylsilyloxy)prop-1-en-2-yl)cyclohex-2-enone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 13154-24-0
triisopropylsilyl chloride

: 151910-94-0
(R)-(-)-2-Methyl-5-<1-(hydroxymethyl)vinyl>cyclohex-2-enon

: 1404195-48-7
(R)-2-methyl-5-(3-(triisopropylsilyloxy)prop-1-en-2-yl)cyclohex-2-enone

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; at 0 - 20 ℃; for 1.66h; Inert atmosphere;
DOI:10.1021/ol302570k DOI:10.1021/ol302570k

Reference yield:

: 6485-40-1,2244-16-8
(R)-Carvone

: 1404195-48-7
(R)-2-methyl-5-(3-(triisopropylsilyloxy)prop-1-en-2-yl)cyclohex-2-enone

Guidance literature:: Multi-step reaction with 3 steps

1: calcium hypochlorite / water; dichloromethane / 7 h / Cooling with ice

2: sodium hydrogencarbonate / water; 1,4-dioxane / 15 h / 100 °C

3: 1H-imidazole / N,N-dimethyl-formamide / 1.66 h / 0 - 20 °C / Inert atmosphere

With 1H-imidazole; calcium hypochlorite; sodium hydrogencarbonate; In 1,4-dioxane; dichloromethane; water; N,N-dimethyl-formamide;
DOI:10.1021/ol302570k DOI:10.1021/ol302570k

Reference yield:

: 82044-96-0
(R)-(-)-2-Methyl-5-<1-(chlormethyl)vinyl>cyclohex-2-enon

: 1404195-48-7
(R)-2-methyl-5-(3-(triisopropylsilyloxy)prop-1-en-2-yl)cyclohex-2-enone

Guidance literature:: Multi-step reaction with 2 steps

1: sodium hydrogencarbonate / water; 1,4-dioxane / 15 h / 100 °C

2: 1H-imidazole / N,N-dimethyl-formamide / 1.66 h / 0 - 20 °C / Inert atmosphere

With 1H-imidazole; sodium hydrogencarbonate; In 1,4-dioxane; water; N,N-dimethyl-formamide;
DOI:10.1021/ol302570k DOI:10.1021/ol302570k