1,10-phenanthrolinebis(pentafluorophenylthiolato)platinum(II)

Base Information

• Chemical Name: 1,10-phenanthrolinebis(pentafluorophenylthiolato)platinum(II)
• CAS No.: 620966-85-0
• Molecular Formula: C₂₄H₈F₁₀N₂PtS₂
• Molecular Weight: 773.537
• Mol file: 620966-85-0.mol

Synonyms:1,10-phenanthrolinebis(pentafluorophenylthiolato)platinum(II)

Chemical Property of 1,10-phenanthrolinebis(pentafluorophenylthiolato)platinum(II)

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,10-phenanthrolinebis(pentafluorophenylthiolato)platinum(II)

There total 2 articles about 1,10-phenanthrolinebis(pentafluorophenylthiolato)platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

dichloro(1,10-phenanthroline)platinum(II) (18432-95-6) + lead pentafluorothiophenolate (21459-27-8) → 1,10-phenanthrolinebis(pentafluorophenylthiolato)platinum(II) (620966-85-0)

Guidance literature:

In 1,2-dichloro-ethane; acetone; for 24h; Reflux;

DOI:10.1016/j.jinorgbio.2020.111206

Reference yield: 80.0%

dichloro(1,10-phenanthroline)platinum(II) (18432-95-6) + pentafluorophenylthiol (771-62-0) → 1,10-phenanthrolinebis(pentafluorophenylthiolato)platinum(II) (620966-85-0)

Guidance literature:

With hexamethylenetetraamine; KO-t-Bu; In ethanol; under N2; degassed soln. of ligand contg. KO-t-Bu in EtOH added dropwiseto mixt. of Pt complex and hexamethylenetetraamine in degassed EtOH; he ated (water bath) with stirring for ca. 4 h; filtered; ppt. washed with hot water and EtOH; dried under vac. overnight; elem. anal.;

DOI:10.1021/ic026286l

Reference yield:

1,10-phenanthrolinebis(pentafluorophenylthiolato)platinum(II) (620966-85-0) → Pt(N2C12H8)(SC6F5)2(1-)

Guidance literature:

With n-Bu₄NBF₄; In N,N-dimethyl-formamide; Electrochem. Process; Pt complex in DMF contg. n-Bu4NBF4 electrochemically reduced; not isolated; monitored by UV-vis spectra;

DOI:10.1021/ic026286l

upstream raw materials:

dichloro(1,10-phenanthroline)platinum(II)

pentafluorophenylthiol

lead pentafluorothiophenolate

Refernces

• 1、 Weinstein, Julia A.,Blake, Alexander J.,Davies, E. Stephen,Davis, Adrienne L.,George, Michael W.,Grills, David C.,Lileev, Igor V.,Maksimov, Alexander M.,Matousek, Pavel,Mel'Nikov, Mikhail Ya.,Parker, Anthony W.,Platonov, Vyacheslav E.,Towrie, Michael,Wilson, Claire,Zheligovskaya, Natalia N.. "PtII Diimine Chromophores with Perfluorinated Thiolate Ligands: Nature and Dynamics of the Charge-Transfer-to-Diimine Lowest Excited State". . p. 7077 - 7085. Retrieved 2008/10/08.