Technology Process of 13-phenylethynyl-15,15-dioctyl-15H-indeno[1,2-i]phenanthro[4,5-abc]phenazine
There total 9 articles about 13-phenylethynyl-15,15-dioctyl-15H-indeno[1,2-i]phenanthro[4,5-abc]phenazine which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine;
for 24h;
Reflux;
Inert atmosphere;
DOI:10.1016/j.dyepig.2014.04.042
- Guidance literature:
-
Multi-step reaction with 8 steps
1.1: potassium hydroxide / dimethyl sulfoxide / 0.5 h / 20 °C
1.2: 5 h / 20 °C
2.1: iron(III) chloride hexahydrate; pyrographite / methanol / 0.17 h / Inert atmosphere; Reflux
2.2: 2 h / Inert atmosphere; Reflux
3.1: acetic acid / 4 h / 20 °C
4.1: acetic acid; nitric acid / 0.5 h / 0 °C
5.1: sulfuric acid / ethanol / 2 h / 80 °C
6.1: iron(III) chloride hexahydrate; pyrographite / methanol / 0.17 h / Reflux; Inert atmosphere
6.2: 2 h / Reflux; Inert atmosphere
7.1: acetic acid; potassium carbonate / Reflux; Inert atmosphere
8.1: bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine / 24 h / Reflux; Inert atmosphere
With
bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; iron(III) chloride hexahydrate; sulfuric acid; nitric acid; potassium carbonate; pyrographite; acetic acid; triethylamine; potassium hydroxide;
In
methanol; ethanol; dimethyl sulfoxide;
8.1: |Sonogashira Cross-Coupling;
DOI:10.1016/j.dyepig.2014.04.042
- Guidance literature:
-
Multi-step reaction with 9 steps
1.1: bromine / dichloromethane / 20 °C
2.1: potassium hydroxide / dimethyl sulfoxide / 0.5 h / 20 °C
2.2: 5 h / 20 °C
3.1: iron(III) chloride hexahydrate; pyrographite / methanol / 0.17 h / Inert atmosphere; Reflux
3.2: 2 h / Inert atmosphere; Reflux
4.1: acetic acid / 4 h / 20 °C
5.1: acetic acid; nitric acid / 0.5 h / 0 °C
6.1: sulfuric acid / ethanol / 2 h / 80 °C
7.1: iron(III) chloride hexahydrate; pyrographite / methanol / 0.17 h / Reflux; Inert atmosphere
7.2: 2 h / Reflux; Inert atmosphere
8.1: acetic acid; potassium carbonate / Reflux; Inert atmosphere
9.1: bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine / 24 h / Reflux; Inert atmosphere
With
bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; iron(III) chloride hexahydrate; sulfuric acid; bromine; nitric acid; potassium carbonate; pyrographite; acetic acid; triethylamine; potassium hydroxide;
In
methanol; ethanol; dichloromethane; dimethyl sulfoxide;
9.1: |Sonogashira Cross-Coupling;
DOI:10.1016/j.dyepig.2014.04.042