RuHBH₄(C₆H₅P(CH₂CH₂CH₂P(C₆H₅)2)2)

Base Information

• Chemical Name: RuHBH₄(C₆H₅P(CH₂CH₂CH₂P(C₆H₅)2)2)
• CAS No.: 81624-51-3
• Molecular Formula: C₃₆H₄₂BP₃Ru
• Molecular Weight: 679.532
• Mol file: 81624-51-3.mol

Synonyms:RuHBH₄(C₆H₅P(CH₂CH₂CH₂P(C₆H₅)2)2)

Chemical Property of RuHBH₄(C₆H₅P(CH₂CH₂CH₂P(C₆H₅)2)2)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of RuHBH₄(C₆H₅P(CH₂CH₂CH₂P(C₆H₅)2)2)

There total 3 articles about RuHBH₄(C₆H₅P(CH₂CH₂CH₂P(C₆H₅)2)2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

sodium tetrahydroborate (16940-66-2) + RuCl2(C6H5P(CH2CH2CH2P(C6H5)2)2)(x) (81616-72-0) → RuHBH4(C6H5P(CH2CH2CH2P(C6H5)2)2) (81624-51-3)

Guidance literature:

In tetrahydrofuran; mixt. of Ru-complex and NaBH4 in THF was heated to reflux for 2 h underN2; soln. was evapd. to dryness in vac., ppt. was extd. with benzene, liq. was reduced at ca. 50°C, allowed to cool, diluted with Et2O, ppt.was collected by filtration, washed with Et2O, dried in vac.; elem. anal.;

DOI:10.1021/ja00378a019

Reference yield: 75.0%

sodium tetrahydroborate (16940-66-2) + Ru(2+)*2Cl(1-)*C6H5P((CH2)3P(C6H5)2)2=RuCl2(C6H5P((CH2)3P(C6H5)2)2) → RuHBH4(C6H5P(CH2CH2CH2P(C6H5)2)2) (81624-51-3)

Guidance literature:

In tetrahydrofuran; Ru-compd. treated with excess of NaBH4 in refluxing THF;

DOI:10.1039/c39820000356

Reference yield:

sodium tetrahydroborate (16940-66-2) + Ru(2+)*2Cl(1-)*C6H5P((CH2)3P(C6H5)2)2=RuCl2(C6H5P((CH2)3P(C6H5)2)2) → RuH(η2-BH4)(bis(3-(diphenylphosphino)propyl)phenylphosphine) (81624-51-3)

Guidance literature:

In not given; Ru complex reacted with excess NaBH4;

DOI:10.1021/om00078a001

upstream raw materials:

sodium tetrahydroborate

RuCl₂(C₆H₅P(CH₂CH₂CH₂P(C₆H₅)2)2)(x)

Downstream raw materials:

cis-{RuH(CH₃CN)2(bis(3-(diphenylphosphino)propyl)phenylphosphine)}BF₄

cis-{RuH(CO)2(bis(3-(diphenylphosphino)propyl)phenylphosphine)}BF₄

trans-{RuH(P(OMe)3)2(bis(3-(diphenylphosphino)propyl)phenylphosphine)}BF₄

cis-RuH₂(P(OMe₃)3)(bis(3-(diphenylphosphino)propyl)phenylphosphine)