2-O-acetyl-4-O-benzyl-3-(2',3',4'-tri-O-benzyl-α-L-rhamnopyranosyl)-α-L-rhamnopyranosyl thiol

Base Information

Chemical Name:2-O-acetyl-4-O-benzyl-3-(2',3',4'-tri-O-benzyl-α-L-rhamnopyranosyl)-α-L-rhamnopyranosyl thiol
CAS No.:1309779-42-7
Molecular Formula:C₄₂H₄₈O₉S
Molecular Weight:728.904
Hs Code.:

Synonyms:2-O-acetyl-4-O-benzyl-3-(2',3',4'-tri-O-benzyl-α-L-rhamnopyranosyl)-α-L-rhamnopyranosyl thiol

Suppliers and Price of 2-O-acetyl-4-O-benzyl-3-(2',3',4'-tri-O-benzyl-α-L-rhamnopyranosyl)-α-L-rhamnopyranosyl thiol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 2-O-acetyl-4-O-benzyl-3-(2',3',4'-tri-O-benzyl-α-L-rhamnopyranosyl)-α-L-rhamnopyranosyl thiol

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 2-O-acetyl-4-O-benzyl-3-(2',3',4'-tri-O-benzyl-α-L-rhamnopyranosyl)-α-L-rhamnopyranosyl thiol

There total 7 articles about 2-O-acetyl-4-O-benzyl-3-(2',3',4'-tri-O-benzyl-α-L-rhamnopyranosyl)-α-L-rhamnopyranosyl thiol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 1309779-41-6
5-nitro-2-pyridyl 2-O-acetyl-4-O-benzyl-3-(2',3',4'-tri-O-benzyl-α-L-rhamnosyl)-α-L-rhamnopyranosyl disulfide

: 1309779-42-7
2-O-acetyl-4-O-benzyl-3-(2',3',4'-tri-O-benzyl-α-L-rhamnopyranosyl)-α-L-rhamnopyranosyl thiol

Guidance literature:: With tributylphosphine; In 1,4-dioxane; chloroform; water; Inert atmosphere;
DOI:10.1002/anie.201006327

Reference yield:

: 1309779-31-4
5-nitro-2-pyridyl 2-O-acetyl-3-O-triethylsilyl-4-O-benzyl-α-L-rhamnopyranosyl disulfide

: 1309779-42-7
2-O-acetyl-4-O-benzyl-3-(2',3',4'-tri-O-benzyl-α-L-rhamnopyranosyl)-α-L-rhamnopyranosyl thiol

Guidance literature:: Multi-step reaction with 3 steps

1.1: triethylamine tris(hydrogen fluoride) / tetrahydrofuran / 4 h / Inert atmosphere

2.1: N-(phenylthio)-ε-caprolactam; 2,4,6-tri-tertbutylpyridine / dichloromethane / 1 h / Inert atmosphere; Molecular sieve

2.2: 1.5 h / -10 °C / Inert atmosphere

3.1: tributylphosphine / 1,4-dioxane; chloroform; water / Inert atmosphere

With N-(phenylthio)-ε-caprolactam; 2,4,6-tri-tertbutylpyridine; tributylphosphine; triethylamine tris(hydrogen fluoride); In tetrahydrofuran; 1,4-dioxane; dichloromethane; chloroform; water;
DOI:10.1002/anie.201006327

Reference yield:

: 1309779-33-6
5-nitro-2-pyridyl 2-O-acetyl-4-O-benzyl-α-L-rhamnopyranosyl disulfide

: 1309779-42-7
2-O-acetyl-4-O-benzyl-3-(2',3',4'-tri-O-benzyl-α-L-rhamnopyranosyl)-α-L-rhamnopyranosyl thiol

Guidance literature:: Multi-step reaction with 2 steps

1.1: N-(phenylthio)-ε-caprolactam; 2,4,6-tri-tertbutylpyridine / dichloromethane / 1 h / Inert atmosphere; Molecular sieve

1.2: 1.5 h / -10 °C / Inert atmosphere

2.1: tributylphosphine / 1,4-dioxane; chloroform; water / Inert atmosphere

With N-(phenylthio)-ε-caprolactam; 2,4,6-tri-tertbutylpyridine; tributylphosphine; In 1,4-dioxane; dichloromethane; chloroform; water;
DOI:10.1002/anie.201006327