<1-(phenylseleno)cyclobutyl>triphenylphosphonium perchlorate

Base Information

• Chemical Name: <1-(phenylseleno)cyclobutyl>triphenylphosphonium perchlorate
• CAS No.: 86046-71-1
• Molecular Formula: C₂₈H₂₆PSe*ClO₄
• Molecular Weight: 571.899
• Mol file: 86046-71-1.mol

Synonyms:<1-(phenylseleno)cyclobutyl>triphenylphosphonium perchlorate

Chemical Property of <1-(phenylseleno)cyclobutyl>triphenylphosphonium perchlorate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of <1-(phenylseleno)cyclobutyl>triphenylphosphonium perchlorate

There total 3 articles about <1-(phenylseleno)cyclobutyl>triphenylphosphonium perchlorate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

<1-(phenylseleno)cyclobutyl>triphenylphosphonium bromide (86046-87-9) → <1-(phenylseleno)cyclobutyl>triphenylphosphonium perchlorate (86046-71-1)

Guidance literature:

With silver perchlorate; In dichloromethane;

DOI:10.1021/jo00163a029

Reference yield:

Phenylselenyl bromide (34837-55-3) → <1-(phenylseleno)cyclobutyl>triphenylphosphonium perchlorate (86046-71-1)

Guidance literature:

Multi-step reaction with 2 steps

1: 89 percent / tetrahydrofuran / -75 °C

2: 90 percent / silver perchlorate / CH₂Cl₂

With silver perchlorate; In tetrahydrofuran; dichloromethane;

DOI:10.1021/jo00163a029

Reference yield:

cyclobutyltriphenylphosphonium ylide (53213-06-2,99503-19-2) → <1-(phenylseleno)cyclobutyl>triphenylphosphonium perchlorate (86046-71-1)

Guidance literature:

Multi-step reaction with 2 steps

1: 89 percent / tetrahydrofuran / -75 °C

2: 90 percent / silver perchlorate / CH₂Cl₂

With silver perchlorate; In tetrahydrofuran; dichloromethane;

DOI:10.1021/jo00163a029

upstream raw materials:

<1-(phenylseleno)cyclobutyl>triphenylphosphonium bromide

Phenylselenyl bromide

cyclobutyltriphenylphosphonium ylide

Downstream raw materials:

(1-cyclobutenyl)triphenylphosphonium perchlorate

(trans-4,5-bis(ethoxycarbonyl)-1-cyclohexenyl)diphenylphosphine oxide

(cis-4,5-bis(ethoxycarbonyl)-1-cyclohexenyl)diphenylphosphine oxide

N-phenyl-1,2,3,6-tetrahydro-4-(diphenylphosphinyl)phthalimide