[5,15-bis(anthracen-9-yl)-10,20-diphenylporphyrinato]nickel(II)

Base Information

• Chemical Name: [5,15-bis(anthracen-9-yl)-10,20-diphenylporphyrinato]nickel(II)
• CAS No.: 1279603-64-3
• Molecular Formula: C₆₀H₃₆N₄Ni
• Molecular Weight: 871.663
• Mol file: 1279603-64-3.mol

Synonyms:[5,15-bis(anthracen-9-yl)-10,20-diphenylporphyrinato]nickel(II)

Chemical Property of [5,15-bis(anthracen-9-yl)-10,20-diphenylporphyrinato]nickel(II)

Chemical Property:

Purity/Quality:

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Technology Process of [5,15-bis(anthracen-9-yl)-10,20-diphenylporphyrinato]nickel(II)

There total 1 articles about [5,15-bis(anthracen-9-yl)-10,20-diphenylporphyrinato]nickel(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

(5,15-dibromo-10,20-diphenylporphyrinato)nickel(II) (193265-36-0) + 2-anthracen-9-yl-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane (709022-63-9) → [5,15-bis(anthracen-9-yl)-10,20-diphenylporphyrinato]nickel(II) (1279603-64-3)

Guidance literature:

With Cs₂CO₃; catalyst: PdCl₂(PPh₃)2/AsPh₃; In tetrahydrofuran; Suzuki cross-coupling; to stirred slurry of Cs2CO3 in THF, bromoporphyrin, borylanthracene and PdCl2(PPh3)2/AsPh3 added; react. mixt. heated to 67°C; shielded from light, stirred overnight; mixt. washed with NaHCO3-satd. water; dried over Na2SO4; org. solvent evapd.; crude mixt. dry-loaded onto silica column; anthracenylporphyrin isolated using CH2Cl2/n-hexane (1:2) as mobile phase; solvent removed; recrystd. from CH2Cl2/MeOH;

DOI:10.1515/znb-2010-1211

upstream raw materials:

(5,15-dibromo-10,20-diphenylporphyrinato)nickel(II)

2-anthracen-9-yl-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane