[5,15-bis[4-(2-diphenylphosphanylethoxy)phenyl]-10,20-bis(mesityl)porphyrinato]zinc(II)

Base Information

• Chemical Name: [5,15-bis[4-(2-diphenylphosphanylethoxy)phenyl]-10,20-bis(mesityl)porphyrinato]zinc(II)
• CAS No.: 919992-18-0
• Molecular Formula: C₇₈H₆₆N₄O₂P₂Zn
• Molecular Weight: 1218.75

Synonyms:[5,15-bis[4-(2-diphenylphosphanylethoxy)phenyl]-10,20-bis(mesityl)porphyrinato]zinc(II)

Chemical Property of [5,15-bis[4-(2-diphenylphosphanylethoxy)phenyl]-10,20-bis(mesityl)porphyrinato]zinc(II)

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Technology Process of [5,15-bis[4-(2-diphenylphosphanylethoxy)phenyl]-10,20-bis(mesityl)porphyrinato]zinc(II)

There total 1 articles about [5,15-bis[4-(2-diphenylphosphanylethoxy)phenyl]-10,20-bis(mesityl)porphyrinato]zinc(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

[5,15-bis(4-[2-(diphenylphosphinothioyl)ethoxy]phenyl)-10,20-bis(mesityl)porphyrinato]zinc(II) (919992-17-9) → [5,15-bis[4-(2-diphenylphosphanylethoxy)phenyl]-10,20-bis(mesityl)porphyrinato]zinc(II) (919992-18-0)

Guidance literature:

With Cp₂ZnHCl; In tetrahydrofuran; under N2; Zn-porphyrin complex and Cp2ZnHCl (excess) in THF stirred at 60°C for 4 h; solvent removed; purified by column chromy. under N2 (silica gel, THF); solvent removed in vac.; elem. anal.;

DOI:10.1021/ja0661010

Reference yield: 94.0%

di(rhodium)tetracarbonyl dichloride + [5,15-bis[4-(2-diphenylphosphanylethoxy)phenyl]-10,20-bis(mesityl)porphyrinato]zinc(II) (919992-18-0) → [([5,15-bis[4-(2-diphenylphosphanylethoxy)phenyl]-10,20-bis(mesityl)porphyrinato]zinc(II))RhCl(CO)]2

Guidance literature:

In tetrahydrofuran; dichloromethane; under N2; soln. of Rh complex in CH2Cl2 stirred for 1 min; soln. of Zn coplex in THF added dropwise over 1 min; stirred for 3 h; solvent removed; recrystd. from CH2Cl2-pentane; elem. anal.;

DOI:10.1021/ja0661010

Reference yield: 93.0%

chloro(1,5-cyclooctadiene)rhodium(I) dimer + [5,15-bis[4-(2-diphenylphosphanylethylsulfanyl)phenyl]-10,20-bis(mesityl)porphyrinato]zinc(II) (919992-24-8) + [5,15-bis[4-(2-diphenylphosphanylethoxy)phenyl]-10,20-bis(mesityl)porphyrinato]zinc(II) (919992-18-0) → [Zn(C20H8N4(C6H2(CH3)3)2(C6H4OC2H4P(C6H5)2)2)Rh2Cl2((((C6H5)2PC2H4S)C6H4)2C20H8N4(C6H2(CH3)3)2)Zn]

Guidance literature:

In tetrahydrofuran; Sonication; THF added to a mixt. of complexes, sonicated for 1 h;

DOI:10.1021/ic701424j

upstream raw materials:

[5,15-bis(4-[2-(diphenylphosphinothioyl)ethoxy]phenyl)-10,20-bis(mesityl)porphyrinato]zinc(II)

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