2,3,7-trideoxy-3,7-imino-4,5-O-isopropylidene-1-C-phenyl-6-O-trimethylsilyl-D-gluco-hept-1-ulose

Base Information

Chemical Name:2,3,7-trideoxy-3,7-imino-4,5-O-isopropylidene-1-C-phenyl-6-O-trimethylsilyl-D-gluco-hept-1-ulose
CAS No.:161365-47-5
Molecular Formula:C₁₉H₂₉NO₄Si
Molecular Weight:363.529
Hs Code.:

Synonyms:2,3,7-trideoxy-3,7-imino-4,5-O-isopropylidene-1-C-phenyl-6-O-trimethylsilyl-D-gluco-hept-1-ulose

Suppliers and Price of 2,3,7-trideoxy-3,7-imino-4,5-O-isopropylidene-1-C-phenyl-6-O-trimethylsilyl-D-gluco-hept-1-ulose

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 2,3,7-trideoxy-3,7-imino-4,5-O-isopropylidene-1-C-phenyl-6-O-trimethylsilyl-D-gluco-hept-1-ulose

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 2,3,7-trideoxy-3,7-imino-4,5-O-isopropylidene-1-C-phenyl-6-O-trimethylsilyl-D-gluco-hept-1-ulose

There total 9 articles about 2,3,7-trideoxy-3,7-imino-4,5-O-isopropylidene-1-C-phenyl-6-O-trimethylsilyl-D-gluco-hept-1-ulose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1-amino-1-deoxy-3,4;5,6-di-O-isopropylidene-D-glucitol p-toluenesulfonate

: 161365-47-5
2,3,7-trideoxy-3,7-imino-4,5-O-isopropylidene-1-C-phenyl-6-O-trimethylsilyl-D-gluco-hept-1-ulose

Guidance literature:: Multi-step reaction with 6 steps

1: 95 percent / K₂CO₃ / H₂O; methanol / 0.42 h / 20 °C

2: pyridinium p-toluenesulfonate / methanol; H₂O / 2 h / 60 °C

3: sodium periodate / H₂O / 0.08 h

4: 0.755 g / MeONa / methanol / 0.5 h / 0 °C

5: CH₂Cl₂ / 0.08 h / 20 °C

6: 0.251 g / Et₃N / CH₂Cl₂ / 0.33 h

With sodium periodate; sodium methylate; pyridinium p-toluenesulfonate; potassium carbonate; triethylamine; In methanol; dichloromethane; water; 1: Acylation / 2: Hydrolysis / 3: Oxidation / 4: Wittig reaction / 5: silylation; deacylation / 6: Cyclization;
DOI:10.1016/S0040-4020(97)00794-1

Reference yield:

: 161365-40-8
[(S)-2-((4R,5S)-5-Formyl-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-hydroxy-ethyl]-carbamic acid tert-butyl ester

: 161365-47-5
2,3,7-trideoxy-3,7-imino-4,5-O-isopropylidene-1-C-phenyl-6-O-trimethylsilyl-D-gluco-hept-1-ulose

Guidance literature:: Multi-step reaction with 3 steps

1: 0.755 g / MeONa / methanol / 0.5 h / 0 °C

2: CH₂Cl₂ / 0.08 h / 20 °C

3: 0.251 g / Et₃N / CH₂Cl₂ / 0.33 h

With sodium methylate; triethylamine; In methanol; dichloromethane; 1: Wittig reaction / 2: silylation; deacylation / 3: Cyclization;
DOI:10.1016/S0040-4020(97)00794-1

Reference yield:

: 161365-39-5
1-(N-tert-butoxycarbonyl)amino-1-deoxy-3,4-O-isopropylidene-D-glucitol

: 161365-47-5
2,3,7-trideoxy-3,7-imino-4,5-O-isopropylidene-1-C-phenyl-6-O-trimethylsilyl-D-gluco-hept-1-ulose

Guidance literature:: Multi-step reaction with 4 steps

1: sodium periodate / H₂O / 0.08 h

2: 0.755 g / MeONa / methanol / 0.5 h / 0 °C

3: CH₂Cl₂ / 0.08 h / 20 °C

4: 0.251 g / Et₃N / CH₂Cl₂ / 0.33 h

With sodium periodate; sodium methylate; triethylamine; In methanol; dichloromethane; water; 1: Oxidation / 2: Wittig reaction / 3: silylation; deacylation / 4: Cyclization;
DOI:10.1016/S0040-4020(97)00794-1