Octyla-D-mannopyranoside

Base Information

• Chemical Name: Octyla-D-mannopyranoside
• CAS No.: 124650-29-9
• Molecular Formula: C₁₄H₂₈O₆
• Molecular Weight: 292.373
• Mol file: 124650-29-9.mol

Synonyms:octyl α-D-mannopyranoside

Chemical Property of Octyla-D-mannopyranoside

Chemical Property:

Purity/Quality:

98% ^*data from raw suppliers

Octyl a-D-mannopyranoside ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Octyla-D-mannopyranoside

There total 8 articles about Octyla-D-mannopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

n-octyl 2,3,4,6-tetra-O-acetyl-β-D-mannopyranoside (128299-96-7) → 1-octyl-β-D-mannopyranoside (6801-93-0,29781-80-4,29836-26-8,40427-75-6,124650-29-9,140147-38-2,142925-45-9,142925-47-1,149342-80-3,149342-81-4)

Guidance literature:

With sodium methylate; In methanol; at 20 ℃; Inert atmosphere;

DOI:10.1039/c4md00122b

Reference yield:

octanol (111-87-5) → 1-octyl-β-D-mannopyranoside (6801-93-0,29781-80-4,29836-26-8,40427-75-6,124650-29-9,140147-38-2,142925-45-9,142925-47-1,149342-80-3,149342-81-4)

Guidance literature:

Multi-step reaction with 2 steps

1: TMSOTf / 0.5 h / -78 °C

2: cyclohexene / Pd(OH)2 / methanol / 12 h

With trimethylsilyl trifluoromethanesulfonate; cyclohexene; palladium dihydroxide; In methanol; 1: transglycosylation / 2: debenzylation;

DOI:10.1016/S0960-894X(00)00330-9

Reference yield:

n-octyl 2,3,4,6-tetra-O-benzyl-β-D-mannopyranoside (267890-72-2) → 1-octyl-β-D-mannopyranoside (6801-93-0,29781-80-4,29836-26-8,40427-75-6,124650-29-9,140147-38-2,142925-45-9,142925-47-1,149342-80-3,149342-81-4)

Guidance literature:

With cyclohexene; palladium dihydroxide; In methanol; for 12h;

DOI:10.1016/S0960-894X(00)00330-9

upstream raw materials:

n-octyl 2,3,4,6-tetra-O-benzyl-β-D-mannopyranoside

octanol

D-Mannose

n-octyl 2,3,4,6-tetra-O-acetyl-β-D-mannopyranoside

Downstream raw materials:

Octyl endo-2,3:4,5-di-O-benzylidene-β-D-mannopyranoside

Octyl exo-2,3:4,6-di-O-benzylidene-β-D-mannopyranoside

C₃₃H₄₂O₆

octyl 6-O-triphenylmethyl-α-D-mannopyranoside