C₂₉H₄₁NO₃S₂Si

Base Information

Chemical Name:C₂₉H₄₁NO₃S₂Si
CAS No.:1416466-29-9
Molecular Formula:C₂₉H₄₁NO₃S₂Si
Molecular Weight:543.867
Hs Code.:

C<sub>29</sub>H<sub>41</sub>NO<sub>3</sub>S<sub>2</sub>Si

Synonyms:C₂₉H₄₁NO₃S₂Si

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Chemical Property of C₂₉H₄₁NO₃S₂Si

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Technology Process of C₂₉H₄₁NO₃S₂Si

There total 1 articles about C₂₉H₄₁NO₃S₂Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1140194-79-1
4-(tert-butyldiphenylsiloxy)butanal dimethyl acetal

: 101979-45-7
(S)-3-acetyl-4-isopropyl-1,3-thiazolidine-2-thione

: C₂₉H₄₁NO₃S₂Si

: 1416466-29-9
C₂₉H₄₁NO₃S₂Si

Guidance literature:: (S)-3-acetyl-4-isopropyl-1,3-thiazolidine-2-thione; With titanium tetrachloride; In dichloromethane; at 0 ℃; for 0.0833333h; Inert atmosphere;

With N-ethyl-N,N-diisopropylamine; In dichloromethane; at -78 - -40 ℃; for 2h; Inert atmosphere;

4-(tert-butyldiphenylsiloxy)butanal dimethyl acetal; With tin(IV) chloride; In dichloromethane; at -78 ℃; for 0.25h; Overall yield = 72 %; Overall yield = 1.57 g; Inert atmosphere;
DOI:10.1039/c2ob26533h

Reference yield: 96.0%

: 1416466-29-9
C₂₉H₄₁NO₃S₂Si

: 1416466-41-5
C₂₃H₃₂O₃Si

Guidance literature:: With diisobutylaluminium hydride; In dichloromethane; toluene; at -78 ℃; for 0.25h; Inert atmosphere;
DOI:10.1039/c2ob26533h

Reference yield:

: 1416466-29-9
C₂₉H₄₁NO₃S₂Si

: malevamide E

Guidance literature:: Multi-step reaction with 12 steps

1.1: diisobutylaluminium hydride / dichloromethane; toluene / 0.25 h / -78 °C / Inert atmosphere

2.1: sodium hydride / tetrahydrofuran / 1 h / -78 - -40 °C / Inert atmosphere

3.1: diisobutylaluminium hydride / tetrahydrofuran; toluene / 0.25 h / -78 °C / Inert atmosphere

4.1: benzene / Inert atmosphere; Reflux

5.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 1 h / 0 - 20 °C / Inert atmosphere

6.1: triethylamine; sulfur trioxide pyridine complex / dichloromethane; dimethyl sulfoxide / 0 - 20 °C / Inert atmosphere

7.1: lithium hexamethyldisilazane / tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide / 0.25 h / -78 °C / Inert atmosphere

7.2: 3 h / -78 °C / Inert atmosphere

8.1: tetrabutyl ammonium fluoride; acetic acid / tetrahydrofuran; N,N-dimethyl-formamide; water / 12 h / 20 - 50 °C / Inert atmosphere

9.1: lithium hydroxide; water / tetrahydrofuran; methanol / 1 h / 0 - 20 °C / Inert atmosphere

10.1: benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride / dichloromethane / 0 °C / Inert atmosphere

10.2: 12 h / 20 °C / Inert atmosphere

11.1: lithium hydroxide; water / tetrahydrofuran; methanol / 1 h / 0 - 20 °C

12.1: 2-methyl-6-nitrobenzoic anhydride; dmap / dichloromethane / 12 h / 20 °C / Inert atmosphere

With dmap; 2-methyl-6-nitrobenzoic anhydride; tetrabutyl ammonium fluoride; water; sulfur trioxide pyridine complex; sodium hydride; diisobutylaluminium hydride; benzotriazol-1-ol; acetic acid; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine; lithium hydroxide; lithium hexamethyldisilazane; In tetrahydrofuran; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; dichloromethane; water; dimethyl sulfoxide; N,N-dimethyl-formamide; toluene; benzene; 2.1: |Wittig-Horner Reaction / 4.1: |Wittig-Horner Reaction / 7.1: |Julia-Kocienski Olefination / 7.2: |Julia-Kocienski Olefination;
DOI:10.1039/c2ob26533h