C₂₉H₃₆O₂Si

Base Information

• Chemical Name: C₂₉H₃₆O₂Si
• CAS No.: 1447958-61-3
• Molecular Formula: C₂₉H₃₆O₂Si
• Molecular Weight: 444.689
• Mol file: 1447958-61-3.mol

Synonyms:C₂₉H₃₆O₂Si

Chemical Property of C₂₉H₃₆O₂Si

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₂₉H₃₆O₂Si

There total 5 articles about C₂₉H₃₆O₂Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3-(tert-butyldiphenylsilyloxy)-1-propanal (112897-03-7) + (1-Benzyl-allyl)-trimethyl-silane → C29H36O2Si (1447958-61-3) + C29H36O2Si (1447958-62-4)

Guidance literature:

3-(tert-butyldiphenylsilyloxy)-1-propanal; (1-Benzyl-allyl)-trimethyl-silane; In dichloromethane; at -78 ℃; for 0.0833333h; Inert atmosphere;

With titanium tetrachloride; In dichloromethane; at -78 ℃; for 3h; Inert atmosphere;

DOI:10.1016/j.tetlet.2013.06.047

Reference yield:

(Z)-3-Phenyl-2-trimethylsilanyl-acrylic acid ethyl ester (58160-83-1) → C29H36O2Si (1447958-61-3) + C29H36O2Si (1447958-62-4)

Guidance literature:

Multi-step reaction with 5 steps

1.1: palladium(II) hydroxide; hydrogen / ethanol / 24 h / 760.05 Torr

2.1: diisobutylaluminium hydride / dichloromethane; toluene / 1 h / -78 °C / Inert atmosphere

3.1: Dess-Martin periodane / dichloromethane / 0.5 h / 20 °C / Inert atmosphere

4.1: n-butyllithium / hexane; tetrahydrofuran / 0.5 h / Inert atmosphere

4.2: 0.17 h / -78 °C / Inert atmosphere

5.1: dichloromethane / 0.08 h / -78 °C / Inert atmosphere

5.2: 3 h / -78 °C / Inert atmosphere

With n-butyllithium; hydrogen; palladium(II) hydroxide; diisobutylaluminium hydride; Dess-Martin periodane; In tetrahydrofuran; ethanol; hexane; dichloromethane; toluene; 4.2: |Wittig Olefination;

DOI:10.1016/j.tetlet.2013.06.047

Reference yield:

3-Phenyl-2-trimethylsilanyl-propionic acid ethyl ester → C29H36O2Si (1447958-61-3) + C29H36O2Si (1447958-62-4)

Guidance literature:

Multi-step reaction with 4 steps

1.1: diisobutylaluminium hydride / dichloromethane; toluene / 1 h / -78 °C / Inert atmosphere

2.1: Dess-Martin periodane / dichloromethane / 0.5 h / 20 °C / Inert atmosphere

3.1: n-butyllithium / hexane; tetrahydrofuran / 0.5 h / Inert atmosphere

3.2: 0.17 h / -78 °C / Inert atmosphere

4.1: dichloromethane / 0.08 h / -78 °C / Inert atmosphere

4.2: 3 h / -78 °C / Inert atmosphere

With n-butyllithium; diisobutylaluminium hydride; Dess-Martin periodane; In tetrahydrofuran; hexane; dichloromethane; toluene; 3.2: |Wittig Olefination;

DOI:10.1016/j.tetlet.2013.06.047

upstream raw materials:

(Z)-3-Phenyl-2-trimethylsilanyl-acrylic acid ethyl ester

3-(tert-butyldiphenylsilyloxy)-1-propanal

C₁₂H₂₀OSi