bromo-acetic acid 1-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-3-oxo-butyl ester

Base Information

Chemical Name:bromo-acetic acid 1-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-3-oxo-butyl ester
CAS No.:890124-16-0
Molecular Formula:C₂₅H₃₃BrO₄Si
Molecular Weight:505.524
Hs Code.:

bromo-acetic acid 1-(<i>tert</i>-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-3-oxo-butyl ester

Synonyms:bromo-acetic acid 1-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-3-oxo-butyl ester

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of bromo-acetic acid 1-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-3-oxo-butyl ester

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Technology Process of bromo-acetic acid 1-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-3-oxo-butyl ester

There total 6 articles about bromo-acetic acid 1-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-3-oxo-butyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 890124-15-9
5-(tert-butyl-diphenyl-silanyloxy)-4-hydroxy-3,3-dimethyl-pentan-2-one

: 598-21-0
2-Bromoacetyl bromide

: 890124-16-0
bromo-acetic acid 1-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-3-oxo-butyl ester

Guidance literature:: With pyridine; In dichloromethane; at 0 ℃;
DOI:10.1016/j.bmcl.2006.03.056

Reference yield:

: 890124-14-8
(R)-2,3,3-Trimethyl-tetrahydro-furan-2,4-diol

: 890124-16-0
bromo-acetic acid 1-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-3-oxo-butyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: Et₃N; DMAP / CH₂Cl₂ / 0 - 20 °C

2: 98 percent / pyridine / CH₂Cl₂ / 0 °C

With pyridine; dmap; triethylamine; In dichloromethane;
DOI:10.1016/j.bmcl.2006.03.056

Reference yield:

: 3-((R)-2,2-Diethyl-[1,3]dioxolan-4-yl)-3-methyl-butan-2-ol

: 890124-16-0
bromo-acetic acid 1-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-3-oxo-butyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: SO₃*pyridine / dimethylsulfoxide / 20 °C

2: aq. HCl / tetrahydrofuran / 0 - 20 °C

3: Et₃N; DMAP / CH₂Cl₂ / 0 - 20 °C

4: 98 percent / pyridine / CH₂Cl₂ / 0 °C

With pyridine; hydrogenchloride; dmap; pyridine-SO₃ complex; triethylamine; In tetrahydrofuran; dichloromethane; dimethyl sulfoxide;
DOI:10.1016/j.bmcl.2006.03.056