1,1-bis(cyclopentadienyl)zircona-2,3,4,5-tetraphenylcyclopentadiene

Base Information

• Chemical Name: 1,1-bis(cyclopentadienyl)zircona-2,3,4,5-tetraphenylcyclopentadiene
• CAS No.: 53433-58-2
• Molecular Formula: C₃₈H₃₀Zr
• Molecular Weight: 577.88
• Mol file: 53433-58-2.mol

Synonyms:1,1-bis(cyclopentadienyl)zircona-2,3,4,5-tetraphenylcyclopentadiene

Chemical Property of 1,1-bis(cyclopentadienyl)zircona-2,3,4,5-tetraphenylcyclopentadiene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,1-bis(cyclopentadienyl)zircona-2,3,4,5-tetraphenylcyclopentadiene

There total 22 articles about 1,1-bis(cyclopentadienyl)zircona-2,3,4,5-tetraphenylcyclopentadiene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

[zirconocene(bis(trimethylsilyl)acetylene)(pyridyl)] + diphenyl acetylene (501-65-5) → 1,1-bis(cyclopentadienyl)zircona-2,3,4,5-tetraphenylcyclopentadiene (53433-58-2)

Guidance literature:

In toluene; at 22 ℃; for 0.166667h; Glovebox;

DOI:10.1002/chem.201902255

Reference yield: 94.0%

zirconocene dichloride (1291-32-3) + diphenyl acetylene (501-65-5) → 1,1-bis(cyclopentadienyl)zircona-2,3,4,5-tetraphenylcyclopentadiene (53433-58-2)

Guidance literature:

With n-butyllithium; In tetrahydrofuran; N2 or Ar atmosphere, treatment of Zr-complex with 2 equiv. of diphenylacetylene (-78 to 25°C);

DOI:10.1021/ja00191a035

Reference yield: 92.0%

(η5-Cp)2(PMePh2)zirconacyclopropene (113192-49-7) + diphenyl acetylene (501-65-5) → 1,1-bis(cyclopentadienyl)zircona-2,3,4,5-tetraphenylcyclopentadiene (53433-58-2)

Guidance literature:

In not given;

DOI:10.1021/ja00191a035

upstream raw materials:

zirconocene dichloride

1,4-dilithio-1,2,3,4-tetraphenylbutadiene

diphenyl acetylene

(η5-Cp)2(PMePh2)zirconacyclopropene

Downstream raw materials:

1,2,3,4-tetraphenyl-1,3-butadiene

cyclopenta-1,3-diene

2,3,4,5-tetraphenylthiophen-1-monoxid

1,1-dichloro-2,3,4,5-tetraphenyl-1-germacyclopenta-2,4-diene