C₃₃H₂₆Cl₂F₆N₅PRu

Base Information

• Chemical Name: C₃₃H₂₆Cl₂F₆N₅PRu
• CAS No.: 1560667-03-9
• Molecular Formula: C₃₃H₂₆Cl₂F₆N₅PRu
• Molecular Weight: 809.543
• Mol file: 1560667-03-9.mol

Synonyms:C₃₃H₂₆Cl₂F₆N₅PRu

Chemical Property of C₃₃H₂₆Cl₂F₆N₅PRu

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

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Technology Process of C₃₃H₂₆Cl₂F₆N₅PRu

There total 5 articles about C₃₃H₂₆Cl₂F₆N₅PRu which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

C15H11Cl3F6N5Ru (1560667-01-7) + triphenylphosphine (603-35-0) → C33H26Cl2F6N5PRu (1560667-03-9)

Guidance literature:

With triethylamine; In ethanol; at 60 ℃; for 3h; Inert atmosphere;

DOI:10.1021/om401144u

Reference yield:

2-bromo-6-(3′,5′-dimethylpyrazolyl)pyridine (134312-61-1) → C33H26Cl2F6N5PRu (1560667-03-9)

Guidance literature:

Multi-step reaction with 5 steps

1: hydrazine hydrate / butan-1-ol / 20 h / 120 °C / Inert atmosphere

2: trifluoroacetic acid / tetrahydrofuran / 12 h / Reflux; Inert atmosphere

3: sulfuric acid / acetic acid / 5 h / Inert atmosphere; Reflux

4: ethanol / 5 h / Inert atmosphere; Reflux

5: triethylamine / ethanol / 3 h / 60 °C / Inert atmosphere

With hydrazine hydrate; sulfuric acid; triethylamine; trifluoroacetic acid; In tetrahydrofuran; ethanol; acetic acid; butan-1-ol;

DOI:10.1021/om401144u

Reference yield:

2-(3,5-dimethyl-1H-pyrazol-1-yl)-6-hydrazinylpyridine (1503344-92-0) → C33H26Cl2F6N5PRu (1560667-03-9)

Guidance literature:

Multi-step reaction with 4 steps

1: trifluoroacetic acid / tetrahydrofuran / 12 h / Reflux; Inert atmosphere

2: sulfuric acid / acetic acid / 5 h / Inert atmosphere; Reflux

3: ethanol / 5 h / Inert atmosphere; Reflux

4: triethylamine / ethanol / 3 h / 60 °C / Inert atmosphere

With sulfuric acid; triethylamine; trifluoroacetic acid; In tetrahydrofuran; ethanol; acetic acid;

DOI:10.1021/om401144u

upstream raw materials:

2-bromo-6-(3′,5′-dimethylpyrazolyl)pyridine

C₁₅H₁₁Cl₃F₆N₅Ru

triphenylphosphine

2-(3,5-dimethyl-1H-pyrazol-1-yl)-6-hydrazinylpyridine