p-methoxyphenyl (2,3,4-tri-O-benzyl-α-L-fucopyranosyl)-(1→2)-(3-O-benzyl-4,6-O-benzylidene-β-D-galactopyranosyl)-(1→3)-(2-azido-4,6-O-benzylidene-2-deoxy-α-D-galactopyranosyl)-(1→3)-2-azido-4,6-O-benzylidene-2-deoxy-α-D-galactopyranoside

Base Information

• Chemical Name: p-methoxyphenyl (2,3,4-tri-O-benzyl-α-L-fucopyranosyl)-(1→2)-(3-O-benzyl-4,6-O-benzylidene-β-D-galactopyranosyl)-(1→3)-(2-azido-4,6-O-benzylidene-2-deoxy-α-D-galactopyranosyl)-(1→3)-2-azido-4,6-O-benzylidene-2-deoxy-α-D-galactopyranoside
• CAS No.: 1410786-19-4
• Molecular Formula: C₈₀H₈₂N₆O₁₉
• Molecular Weight: 1431.56
• Mol file: 1410786-19-4.mol

Synonyms:p-methoxyphenyl (2,3,4-tri-O-benzyl-α-L-fucopyranosyl)-(1→2)-(3-O-benzyl-4,6-O-benzylidene-β-D-galactopyranosyl)-(1→3)-(2-azido-4,6-O-benzylidene-2-deoxy-α-D-galactopyranosyl)-(1→3)-2-azido-4,6-O-benzylidene-2-deoxy-α-D-galactopyranoside

Chemical Property of p-methoxyphenyl (2,3,4-tri-O-benzyl-α-L-fucopyranosyl)-(1→2)-(3-O-benzyl-4,6-O-benzylidene-β-D-galactopyranosyl)-(1→3)-(2-azido-4,6-O-benzylidene-2-deoxy-α-D-galactopyranosyl)-(1→3)-2-azido-4,6-O-benzylidene-2-deoxy-α-D-galactopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of p-methoxyphenyl (2,3,4-tri-O-benzyl-α-L-fucopyranosyl)-(1→2)-(3-O-benzyl-4,6-O-benzylidene-β-D-galactopyranosyl)-(1→3)-(2-azido-4,6-O-benzylidene-2-deoxy-α-D-galactopyranosyl)-(1→3)-2-azido-4,6-O-benzylidene-2-deoxy-α-D-galactopyranoside

There total 1 articles about p-methoxyphenyl (2,3,4-tri-O-benzyl-α-L-fucopyranosyl)-(1→2)-(3-O-benzyl-4,6-O-benzylidene-β-D-galactopyranosyl)-(1→3)-(2-azido-4,6-O-benzylidene-2-deoxy-α-D-galactopyranosyl)-(1→3)-2-azido-4,6-O-benzylidene-2-deoxy-α-D-galactopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

p-methoxyphenyl (3-O-benzyl-4,6-O-benzylidene-β-D-galactopyranosyl)-(1→3)-(2-azido-4,6-O-benzylidene-2-deoxy-α-D-galactopyranosyl)-(1→3)-2-azido-4,6-O-benzylidene-2-deoxy-α-D-galactopyranoside (1410786-17-2) + ethyl 2,3,4-tri-O-benzyl-1-thio-β-L-fucopyranoside (116514-50-2,128962-63-0,131545-02-3,136758-06-0,99409-34-4,116391-11-8) → p-methoxyphenyl (2,3,4-tri-O-benzyl-α-L-fucopyranosyl)-(1→2)-(3-O-benzyl-4,6-O-benzylidene-β-D-galactopyranosyl)-(1→3)-(2-azido-4,6-O-benzylidene-2-deoxy-α-D-galactopyranosyl)-(1→3)-2-azido-4,6-O-benzylidene-2-deoxy-α-D-galactopyranoside (1410786-19-4)

Guidance literature:

With N-iodo-succinimide; perchloric acid adsorbed on silica gel; In diethyl ether; dichloromethane; at -18 ℃; for 1h; diastereoselective reaction; Inert atmosphere; Molecular sieve;

DOI:10.1016/j.tetasy.2012.08.006

Reference yield:

p-methoxyphenyl (2,3,4-tri-O-benzyl-α-L-fucopyranosyl)-(1→2)-(3-O-benzyl-4,6-O-benzylidene-β-D-galactopyranosyl)-(1→3)-(2-azido-4,6-O-benzylidene-2-deoxy-α-D-galactopyranosyl)-(1→3)-2-azido-4,6-O-benzylidene-2-deoxy-α-D-galactopyranoside (1410786-19-4) → C31H50N2O19

Guidance literature:

With triethylsilane; 20% palladium hydroxide-activated charcoal; In methanol; dichloromethane; at 20 ℃; for 6.5h;

DOI:10.1016/j.tetasy.2012.08.006

upstream raw materials:

p-methoxyphenyl (3-O-benzyl-4,6-O-benzylidene-β-D-galactopyranosyl)-(1→3)-(2-azido-4,6-O-benzylidene-2-deoxy-α-D-galactopyranosyl)-(1→3)-2-azido-4,6-O-benzylidene-2-deoxy-α-D-galactopyranoside

ethyl 2,3,4-tri-O-benzyl-1-thio-β-L-fucopyranoside