(η3-allyl)[diphenylbis((4-methylphenyl)imino)phosphorato]nickel

Base Information

• Chemical Name: (η3-allyl)[diphenylbis((4-methylphenyl)imino)phosphorato]nickel
• CAS No.: 888705-58-6
• Molecular Formula: C₂₉H₂₉N₂NiP
• Molecular Weight: 495.226
• Mol file: 888705-58-6.mol

Synonyms:(η3-allyl)[diphenylbis((4-methylphenyl)imino)phosphorato]nickel

Chemical Property of (η3-allyl)[diphenylbis((4-methylphenyl)imino)phosphorato]nickel

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (η3-allyl)[diphenylbis((4-methylphenyl)imino)phosphorato]nickel

There total 1 articles about (η3-allyl)[diphenylbis((4-methylphenyl)imino)phosphorato]nickel which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

bi(allylnickel bromide) + N,N'-bis(4-methylphenyl)diphenyliminophosphonamide (351884-56-5) → (η3-allyl)[diphenylbis((4-methylphenyl)imino)phosphorato]nickel (888705-58-6)

Guidance literature:

With n-BuLi; In tetrahydrofuran; hexane; under N2; ligand in THF cooled to -80°C; n-BuLi in hexanes added;warmed to 20°C; cooled to -80°C; soln. of Ni complex in T HF added; pumped to dryness; dissolved in toluene; filtered through Celite; solvent evapd.; crystd. from CH2Cl2 at -30°C; elem. anal.;

DOI:10.1021/om051103z

upstream raw materials:

N,N'-bis(4-methylphenyl)diphenyliminophosphonamide