2-(2-(2-(3-bromopropoxy)naphth-6-yl)-9,9-diethylfluoren-7-yl)-9,9-diethyl-7-(4-methoxy-phenyl)fluorene

Base Information

Chemical Name:2-(2-(2-(3-bromopropoxy)naphth-6-yl)-9,9-diethylfluoren-7-yl)-9,9-diethyl-7-(4-methoxy-phenyl)fluorene
CAS No.:1403598-91-3
Molecular Formula:C₅₄H₅₁BrO₂
Molecular Weight:811.902
Hs Code.:

Synonyms:2-(2-(2-(3-bromopropoxy)naphth-6-yl)-9,9-diethylfluoren-7-yl)-9,9-diethyl-7-(4-methoxy-phenyl)fluorene

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Chemical Property of 2-(2-(2-(3-bromopropoxy)naphth-6-yl)-9,9-diethylfluoren-7-yl)-9,9-diethyl-7-(4-methoxy-phenyl)fluorene

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Technology Process of 2-(2-(2-(3-bromopropoxy)naphth-6-yl)-9,9-diethylfluoren-7-yl)-9,9-diethyl-7-(4-methoxy-phenyl)fluorene

There total 7 articles about 2-(2-(2-(3-bromopropoxy)naphth-6-yl)-9,9-diethylfluoren-7-yl)-9,9-diethyl-7-(4-methoxy-phenyl)fluorene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.9%

: 1403598-87-7
7-(4-methoxyphenyl)-9,9-diethyl-2-fluorenylboronic acid pinacol ester

: 1403598-90-2
2-(2-(3-bromopropoxy)naphth-6-yl)-7-bromo-9,9-diethylfluorene

: 1403598-91-3
2-(2-(2-(3-bromopropoxy)naphth-6-yl)-9,9-diethylfluoren-7-yl)-9,9-diethyl-7-(4-methoxy-phenyl)fluorene

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate; In ethanol; water; toluene; for 8h; Reflux; Inert atmosphere;
DOI:10.1002/asia.201200299

Reference yield:

: 1094435-38-7
2-(3-bromopropoxy)-6-bromonaphthalene

: 1403598-91-3
2-(2-(2-(3-bromopropoxy)naphth-6-yl)-9,9-diethylfluoren-7-yl)-9,9-diethyl-7-(4-methoxy-phenyl)fluorene

Guidance literature:: Multi-step reaction with 3 steps

1: potassium acetate; bis-triphenylphosphine-palladium(II) chloride / 1,4-dioxane / 12 h / 90 °C / Inert atmosphere

2: tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate / water; ethanol; toluene / 8 h / Reflux; Inert atmosphere

3: tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate / water; ethanol; toluene / 8 h / Reflux; Inert atmosphere

With bis-triphenylphosphine-palladium(II) chloride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium acetate; sodium carbonate; In 1,4-dioxane; ethanol; water; toluene; 2: |Suzuki Coupling / 3: |Suzuki Coupling;
DOI:10.1002/asia.201200299

Reference yield:

: 15231-91-1
6-bromo-naphthalen-2-ol

: 1403598-91-3
2-(2-(2-(3-bromopropoxy)naphth-6-yl)-9,9-diethylfluoren-7-yl)-9,9-diethyl-7-(4-methoxy-phenyl)fluorene

Guidance literature:: Multi-step reaction with 4 steps

1: potassium carbonate / N,N-dimethyl-formamide / 8 h / 80 °C / Inert atmosphere

2: potassium acetate; bis-triphenylphosphine-palladium(II) chloride / 1,4-dioxane / 12 h / 90 °C / Inert atmosphere

3: tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate / water; ethanol; toluene / 8 h / Reflux; Inert atmosphere

4: tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate / water; ethanol; toluene / 8 h / Reflux; Inert atmosphere

With bis-triphenylphosphine-palladium(II) chloride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium acetate; sodium carbonate; potassium carbonate; In 1,4-dioxane; ethanol; water; N,N-dimethyl-formamide; toluene; 3: |Suzuki Coupling / 4: |Suzuki Coupling;
DOI:10.1002/asia.201200299