benzyl tetradec-13-enoate

Base Information

• Chemical Name: benzyl tetradec-13-enoate
• CAS No.: 1574334-34-1
• Molecular Formula: C₂₁H₃₂O₂
• Molecular Weight: 316.484
• Mol file: 1574334-34-1.mol

Synonyms:benzyl tetradec-13-enoate

Chemical Property of benzyl tetradec-13-enoate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of benzyl tetradec-13-enoate

There total 6 articles about benzyl tetradec-13-enoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

11-(dimethyl-t-butylsilyloxy)undecyl bromide (98008-53-8) → benzyl tetradec-13-enoate (1574334-34-1)

Guidance literature:

Multi-step reaction with 5 steps

1: copper(l) iodide / tetrahydrofuran / -78 - 20 °C

2: tetrabutyl ammonium fluoride / tetrahydrofuran / 3 h

3: dimethyl sulfoxide; oxalyl dichloride / dichloromethane / 1 h / -60 - -50 °C

4: sodium chlorite; sodium dihydrogenphosphate dihydrate; 2-methyl-but-2-ene / water; tert-butyl alcohol

5: toluene-4-sulfonic acid / toluene / Reflux

With sodium chlorite; copper(l) iodide; sodium dihydrogenphosphate dihydrate; 2-methyl-but-2-ene; oxalyl dichloride; tetrabutyl ammonium fluoride; toluene-4-sulfonic acid; dimethyl sulfoxide; In tetrahydrofuran; dichloromethane; water; toluene; tert-butyl alcohol;

DOI:10.1039/c3ob42364f

Reference yield:

tetradec-13-enal (85896-31-7) → benzyl tetradec-13-enoate (1574334-34-1)

Guidance literature:

Multi-step reaction with 2 steps

1: sodium chlorite; sodium dihydrogenphosphate dihydrate; 2-methyl-but-2-ene / water; tert-butyl alcohol

2: toluene-4-sulfonic acid / toluene / Reflux

With sodium chlorite; sodium dihydrogenphosphate dihydrate; 2-methyl-but-2-ene; toluene-4-sulfonic acid; In water; toluene; tert-butyl alcohol;

DOI:10.1039/c3ob42364f

Reference yield:

C20H42OSi (1225281-87-7) → benzyl tetradec-13-enoate (1574334-34-1)

Guidance literature:

Multi-step reaction with 4 steps

1: tetrabutyl ammonium fluoride / tetrahydrofuran / 3 h

2: dimethyl sulfoxide; oxalyl dichloride / dichloromethane / 1 h / -60 - -50 °C

3: sodium chlorite; sodium dihydrogenphosphate dihydrate; 2-methyl-but-2-ene / water; tert-butyl alcohol

4: toluene-4-sulfonic acid / toluene / Reflux

With sodium chlorite; sodium dihydrogenphosphate dihydrate; 2-methyl-but-2-ene; oxalyl dichloride; tetrabutyl ammonium fluoride; toluene-4-sulfonic acid; dimethyl sulfoxide; In tetrahydrofuran; dichloromethane; water; toluene; tert-butyl alcohol;

DOI:10.1039/c3ob42364f

upstream raw materials:

11-(dimethyl-t-butylsilyloxy)undecyl bromide

C₂₀H₄₂OSi

tetradec-13-enal

13-tetradecenoic acid

Downstream raw materials:

C₄₈H₇₈O₇Si

C₄₂H₆₄O₇

C₅₅H₇₇NO₁₀

(E)-benzyl-14-((4S,5R)-2,2-dimethyl-5-((R)-oxiran-2-yl)-1,3-dioxolan-4-yl)tetradec-13-enoate