(1R)-2beta-(Benzyloxycarbonylamino)-3-cyclohexene-1beta-carbaldehyde

Base Information

Chemical Name:(1R)-2beta-(Benzyloxycarbonylamino)-3-cyclohexene-1beta-carbaldehyde
CAS No.:1334208-34-2
Molecular Formula:C₁₅H₁₇NO₃
Molecular Weight:259.305
Hs Code.:
DSSTox Substance ID:DTXSID901146250
Nikkaji Number:J2.896.239H

Synonyms:SCHEMBL14327799;DTXSID901146250;(1R)-2beta-(Benzyloxycarbonylamino)-3-cyclohexene-1beta-carbaldehyde;Carbamic acid, N-[(1S,6R)-6-formyl-2-cyclohexen-1-yl]-, phenylmethyl ester;1334208-34-2

Suppliers and Price of (1R)-2beta-(Benzyloxycarbonylamino)-3-cyclohexene-1beta-carbaldehyde

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of (1R)-2beta-(Benzyloxycarbonylamino)-3-cyclohexene-1beta-carbaldehyde

Chemical Property:

XLogP3:2.5
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:5
Exact Mass:259.12084340
Heavy Atom Count:19
Complexity:334

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1CC(C(C=C1)NC(=O)OCC2=CC=CC=C2)C=O
Isomeric SMILES:C1C[C@H]([C@H](C=C1)NC(=O)OCC2=CC=CC=C2)C=O

Technology Process of (1R)-2beta-(Benzyloxycarbonylamino)-3-cyclohexene-1beta-carbaldehyde

There total 3 articles about (1R)-2beta-(Benzyloxycarbonylamino)-3-cyclohexene-1beta-carbaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 71616-72-3
benzyl (buta-1,3-dien-1-yl)carbamate

: 107-02-8,25068-14-8
acrolein

: 1334208-34-2
benzyl (1S,6R)-6-formylcyclohex-2-enylcarbamate

Guidance literature:: acrolein; With C₆₂H₆₄O₈P₂; In toluene; at 20 ℃; for 0.5h; Inert atmosphere; Molecular sieve;

benzyl (buta-1,3-dien-1-yl)carbamate; In toluene; at -80 ℃; for 48h; optical yield given as %ee; enantioselective reaction; Inert atmosphere;
DOI:10.1021/ja2081444

Reference yield:

: 71616-72-3
benzyl (buta-1,3-dien-1-yl)carbamate

: 107-02-8,25068-14-8
acrolein

: 1334208-34-2
benzyl (1S,6R)-6-formylcyclohex-2-enylcarbamate

: C₁₅H₁₇NO₃

Guidance literature:: With C₅₃H₄₁F₅O₈P₂; In toluene; at -80 ℃; Overall yield = 67 %; enantioselective reaction; Molecular sieve;
DOI:10.1021/acscatal.5b02079

Reference yield:

: 71616-72-3
benzyl (buta-1,3-dien-1-yl)carbamate

: 107-02-8,25068-14-8
acrolein

: 1334208-34-2
benzyl (1S,6R)-6-formylcyclohex-2-enylcarbamate

: 323196-37-8
benzyl ((1R,6S)-6-formylcyclohex-2-en-1-yl)carbamate

Guidance literature:: acrolein; With C₄₄H₂₈O₈P₂; In toluene; at 20 ℃; for 0.5h; Inert atmosphere; Molecular sieve;

benzyl (buta-1,3-dien-1-yl)carbamate; In toluene; at -80 ℃; for 48h; optical yield given as %ee; enantioselective reaction; Inert atmosphere;
DOI:10.1021/ja2081444