[(di-tert-butyl-(1-methyl-imidazol-2-yl)phosphine)Pd(phenyl)I]

Base Information

• Chemical Name: [(di-tert-butyl-(1-methyl-imidazol-2-yl)phosphine)Pd(phenyl)I]
• CAS No.: 875439-25-1
• Molecular Formula: C₁₈H₂₈IN₂PPd
• Molecular Weight: 536.732
• Mol file: 875439-25-1.mol

Synonyms:[(di-tert-butyl-(1-methyl-imidazol-2-yl)phosphine)Pd(phenyl)I]

Chemical Property of [(di-tert-butyl-(1-methyl-imidazol-2-yl)phosphine)Pd(phenyl)I]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(di-tert-butyl-(1-methyl-imidazol-2-yl)phosphine)Pd(phenyl)I]

There total 1 articles about [(di-tert-butyl-(1-methyl-imidazol-2-yl)phosphine)Pd(phenyl)I] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

iodobenzene (591-50-4) + bis(di-tert-butyl-(1-methyl-imidazol-2-yl)phosphine)palladium(0) (875439-15-9) → [(di-tert-butyl-(1-methyl-imidazol-2-yl)phosphine)Pd(phenyl)I] (875439-25-1)

Guidance literature:

In benzene; under dry N2 atm. using Schlenk line and glovebox techniques; Pd complexdissolved in benzene; iodobenzene added; soln. mixed; allowed to stand still at room temp. for 24 h; crystals isolated by removing mother liquor; washed (benzene); dried (vac.); elem. anal.;

DOI:10.1021/ja054779u

Reference yield:

[(di-tert-butyl-(1-methyl-imidazol-2-yl)phosphine)Pd(phenyl)I] (875439-25-1) + isopropylamine (75-31-0) + potassium tetrakis(pentafluorophenyl)borate → [(di-tert-butyl-(1-methyl-imidazol-2-yl)phosphine)Pd(phenyl)(isopropylamine)][tetrakis(pentafluorophenyl)borate] (875439-42-2)

Guidance literature:

In dichloromethane-d2; under dry N2 atm. using Schlenk line and glovebox techniques; to Pd complex in CD2Cl2 added isopropylamine; KB(C6F5)4 added; monitored by NMR spectroscopy;

DOI:10.1021/ja054779u

upstream raw materials:

iodobenzene

bis(di-tert-butyl-(1-methyl-imidazol-2-yl)phosphine)palladium⁽⁰⁾

Downstream raw materials:

[(di-tert-butyl-(1-methyl-imidazol-2-yl)phosphine)Pd(phenyl)(isopropylamine)][tetrakis(pentafluorophenyl)borate]