11,11-Dimethyl-10-methylen-4-phenyl-2,4,6-triazatricyclo<5.3.1.0^2,6>undec-8-en-3,5-dion

Base Information

• Chemical Name: 11,11-Dimethyl-10-methylen-4-phenyl-2,4,6-triazatricyclo<5.3.1.0^2,6>undec-8-en-3,5-dion
• CAS No.: 100084-66-0
• Molecular Formula: C₁₇H₁₇N₃O₂
• Molecular Weight: 295.341
• Mol file: 100084-66-0.mol

Synonyms:11,11-Dimethyl-10-methylen-4-phenyl-2,4,6-triazatricyclo<5.3.1.0^2,6>undec-8-en-3,5-dion

Chemical Property of 11,11-Dimethyl-10-methylen-4-phenyl-2,4,6-triazatricyclo<5.3.1.0^2,6>undec-8-en-3,5-dion

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 11,11-Dimethyl-10-methylen-4-phenyl-2,4,6-triazatricyclo<5.3.1.0^2,6>undec-8-en-3,5-dion

There total 3 articles about 11,11-Dimethyl-10-methylen-4-phenyl-2,4,6-triazatricyclo<5.3.1.0^2,6>undec-8-en-3,5-dion which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 51.0%

(1S*,10S*)-10-Hydroxy-1,11,11-trimethyl-4-phenyl-2,4,6-triazatricyclo<5.2.2.02,6>undec-8-en-3,5-dion (100164-19-0) → 11,11-Dimethyl-10-methylen-4-phenyl-2,4,6-triazatricyclo<5.3.1.02,6>undec-8-en-3,5-dion (100084-66-0)

Guidance literature:

With trichlorophosphate; In pyridine; at 110 ℃; for 2.5h;

Reference yield:

4-Phenyl-1,2,4-triazolidine-3,5-dione (4233-33-4) → 11,11-Dimethyl-10-methylen-4-phenyl-2,4,6-triazatricyclo<5.3.1.02,6>undec-8-en-3,5-dion (100084-66-0)

Guidance literature:

Multi-step reaction with 3 steps

1: 95 percent / benzene / 2 h / Heating

2: 33 percent / NaBH₄ / ethanol; propan-2-ol; H₂O / 3 h / Ambient temperature

3: 51 percent / POCl₃ / pyridine / 2.5 h / 110 °C

With sodium tetrahydroborate; trichlorophosphate; In pyridine; ethanol; water; isopropyl alcohol; benzene;

Reference yield:

1,11,11-Trimethyl-4-phenyl-2,4,6-triazatricyclo<5.2.2.02,6>undec-8-en-3,5,10-trion (100084-46-6) → 11,11-Dimethyl-10-methylen-4-phenyl-2,4,6-triazatricyclo<5.3.1.02,6>undec-8-en-3,5-dion (100084-66-0)

Guidance literature:

Multi-step reaction with 2 steps

1: 33 percent / NaBH₄ / ethanol; propan-2-ol; H₂O / 3 h / Ambient temperature

2: 51 percent / POCl₃ / pyridine / 2.5 h / 110 °C

With sodium tetrahydroborate; trichlorophosphate; In pyridine; ethanol; water; isopropyl alcohol;

upstream raw materials:

(1S^*,10S^*)-10-Hydroxy-1,11,11-trimethyl-4-phenyl-2,4,6-triazatricyclo<5.2.2.0^2,6>undec-8-en-3,5-dion

4-Phenyl-1,2,4-triazolidine-3,5-dione

1,11,11-Trimethyl-4-phenyl-2,4,6-triazatricyclo<5.2.2.0^2,6>undec-8-en-3,5,10-trion

Refernces