2,4-Octadienoic acid, 7-(t-butyldimethylsilyloxy)-, methyl ester (E,E) -

Base Information

Chemical Name:2,4-Octadienoic acid, 7-(t-butyldimethylsilyloxy)-, methyl ester (E,E) -
CAS No.:79427-02-4
Molecular Formula:C15H28 O3 Si
Molecular Weight:284.471
Hs Code.:

Synonyms:2,4-Octadienoicacid, 7-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-, methyl ester, (E,E)- (9CI);2,4-Octadienoic acid, 7-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-, methyl ester,(E,E)-(?à)-

Suppliers and Price of 2,4-Octadienoic acid, 7-(t-butyldimethylsilyloxy)-, methyl ester (E,E) -

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of 2,4-Octadienoic acid, 7-(t-butyldimethylsilyloxy)-, methyl ester (E,E) -

Chemical Property:

PSA：35.53000
LogP:4.07220

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 2,4-Octadienoic acid, 7-(t-butyldimethylsilyloxy)-, methyl ester (E,E) -

There total 6 articles about 2,4-Octadienoic acid, 7-(t-butyldimethylsilyloxy)-, methyl ester (E,E) - which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

: 79414-10-1
(2E)-5-(t-Butyl-dimethylsilyloxy)-2-hexen-1-al

: 21204-67-1,2605-67-6
methyl (triphenylphosphoranylidene)acetate

: 79427-02-4
(2E,4E)-7-(t-Butyl-dimethylsilyloxy)-2,4-octadiensaeuremethylester

Guidance literature:: In toluene; at 90 - 95 ℃; for 16h;
DOI:10.1002/hlca.19810640523

Reference yield:

: 92775-37-6,71171-66-9,72150-39-1,116839-04-4
3-((tert-butyldimethylsilyl)oxy)butanal

: 79427-02-4
(2E,4E)-7-(t-Butyl-dimethylsilyloxy)-2,4-octadiensaeuremethylester

Guidance literature:: Multi-step reaction with 4 steps

1: 76 percent / dimethylformamide / 16 h / 90 - 95 °C

2: 96 percent / diisobutylaluminium hydride / pentane; hexane / 1.5 h / -70 - -30 °C

3: 78 percent / CrO₃, pyridine / dimethylformamide / 1.5 h / 0 - 20 °C

4: 63 percent / toluene / 16 h / 90 - 95 °C

With pyridine; chromium(VI) oxide; diisobutylaluminium hydride; In hexane; N,N-dimethyl-formamide; toluene; pentane;
DOI:10.1002/hlca.19810640523

Reference yield:

: 68726-87-4
(3RS)-3-(tert-butyl-dimethyl-silanyloxy)-butan-1-ol

: 79427-02-4
(2E,4E)-7-(t-Butyl-dimethylsilyloxy)-2,4-octadiensaeuremethylester

Guidance literature:: Multi-step reaction with 5 steps

1: 63 percent / CrO₃/pyridine / CH₂Cl₂ / 0.5 h / Ambient temperature

2: 76 percent / dimethylformamide / 16 h / 90 - 95 °C

3: 96 percent / diisobutylaluminium hydride / pentane; hexane / 1.5 h / -70 - -30 °C

4: 78 percent / CrO₃, pyridine / dimethylformamide / 1.5 h / 0 - 20 °C

5: 63 percent / toluene / 16 h / 90 - 95 °C

With pyridine; chromium(VI) oxide; diisobutylaluminium hydride; In hexane; dichloromethane; N,N-dimethyl-formamide; toluene; pentane;
DOI:10.1002/hlca.19810640523