2,4-DI-O-Benzyl-1,3,6-tri-O-acetyl-alpha-D-glucopyranose

Base Information

Chemical Name:2,4-DI-O-Benzyl-1,3,6-tri-O-acetyl-alpha-D-glucopyranose
CAS No.:79414-66-7
Molecular Formula:C₂₆H₃₀O₉
Molecular Weight:486.519
Hs Code.:
DSSTox Substance ID:DTXSID50443281
Nikkaji Number:J2.316.201F
Mol file:79414-66-7.mol

Synonyms:79414-66-7;2,4-DI-O-BENZYL-1,3,6-TRI-O-ACETYL-ALPHA-D-GLUCOPYRANOSE;[(2R,3R,4S,5R,6R)-4,6-diacetyloxy-3,5-bis(phenylmethoxy)oxan-2-yl]methyl acetate;1,3,6-Tri-O-acetyl-2,4-di-O-benzyl-a-D-glucopyranose;1,4,6-TRI-O-ACETYL-2,3-O-CARBONYL-ALPHA-D-MANNOPYRANOSE;DTXSID50443281;ZAUYNTYUSYJZRN-RTJMFUJLSA-N;W-203816;1,3,6-Tri-O-acetyl-2,4-di-O-benzyl-alpha-D-glucopyranose;1-O,3-O,6-O-Triacetyl-2-O,4-O-dibenzyl-alpha-D-glucopyranose

Suppliers and Price of 2,4-DI-O-Benzyl-1,3,6-tri-O-acetyl-alpha-D-glucopyranose

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Usbiological
1,3,6-Tri-O-acetyl-2,4-di-O-benzyl-a-D-glucopyranose
500mg
$ 418.00

TRC
2,4-Di-O-benzyl-1,3,6-tri-O-acetyl-α-D-glucopyranose
10g
$ 970.00

Medical Isotopes, Inc.
2,4-Di-O-benzyl-1,3,6-tri-O-acetyl-α-D-glucopyranose
5 g
$ 1600.00

Medical Isotopes, Inc.
1-3-6-Tri-O-acetyl-2-4-di-O-benzyl-α-D-glucopyranose
2 g
$ 663.00

Biosynth Carbosynth
1,3,6-Tri-O-acetyl-2,4-di-O-benzyl-a-D-glucopyranose
2 g
$ 262.50

Biosynth Carbosynth
1,3,6-Tri-O-acetyl-2,4-di-O-benzyl-a-D-glucopyranose
1 g
$ 168.00

Biosynth Carbosynth
1,3,6-Tri-O-acetyl-2,4-di-O-benzyl-a-D-glucopyranose
500 mg
$ 95.00

American Custom Chemicals Corporation
2,4-DI-O-BENZYL-1,3,6-TRI-O-ACETYL-ALPHA-D-GLUCOPYRANOSE 95.00%
1G
$ 704.55

AK Scientific
1,4,6-Tri-O-acetyl-2,3-O-carbonyl-alpha-D-mannopyranose
2g
$ 404.00

Total 6 raw suppliers

Chemical Property of 2,4-DI-O-Benzyl-1,3,6-tri-O-acetyl-alpha-D-glucopyranose

Chemical Property:

PSA：106.59000
LogP:2.94000
XLogP3:2.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:9
Rotatable Bond Count:13
Exact Mass:486.18898253
Heavy Atom Count:35
Complexity:684

Purity/Quality:

98%Min ^*data from raw suppliers

1,3,6-Tri-O-acetyl-2,4-di-O-benzyl-a-D-glucopyranose ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(=O)OCC1C(C(C(C(O1)OC(=O)C)OCC2=CC=CC=C2)OC(=O)C)OCC3=CC=CC=C3
Isomeric SMILES:CC(=O)OC[C@@H]1[C@H]([C@@H]([C@H]([C@H](O1)OC(=O)C)OCC2=CC=CC=C2)OC(=O)C)OCC3=CC=CC=C3
Uses 2,4-Di-O-benzyl-1,3,6-tri-O-acetyl-α-D-glucopyranose (cas# 79414-66-7) is a compound useful in organic synthesis.

Technology Process of 2,4-DI-O-Benzyl-1,3,6-tri-O-acetyl-alpha-D-glucopyranose

There total 9 articles about 2,4-DI-O-Benzyl-1,3,6-tri-O-acetyl-alpha-D-glucopyranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 108-24-7
acetic anhydride

: 86861-43-0
3-O-Acetyl-1,6-anhydro-2,4-di-O-benzyl-β-D-mannopyranose

: 80738-50-7
1,3,6-tri-O-acetyl-2,4-di-O-benzyl-α-D-mannopyranose

: 79414-66-7,79705-28-5,79705-29-6,80738-50-7,81413-13-0,114283-81-7
Acetic acid (2S,3S,4S,5R,6R)-2-acetoxy-6-acetoxymethyl-3,5-bis-benzyloxy-tetrahydro-pyran-4-yl ester

Guidance literature:: In trifluoroacetic acid; for 12h; Yields of byproduct given; Ambient temperature;

Reference yield:

: 97-30-3
methyl-alpha-D-glucopyranoside

: 79414-66-7
1,3,6-tri-O-acetyl-2,4-di-O-benzyl-α-D-glucopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 94 percent / NaH / dimethylformamide / 24 h / 75 °C

2: conc. H₂SO₄ / 1.5 h / 0 °C

With sulfuric acid; sodium hydride; In N,N-dimethyl-formamide;
DOI:10.1080/00397919708006792

Reference yield:

: 86900-44-9
1,6-anhydro-4-O-benzyl-β-D-mannopyranose

: 79414-66-7,79705-28-5,79705-29-6,80738-50-7,81413-13-0,114283-81-7
Acetic acid (2S,3S,4S,5R,6R)-2-acetoxy-6-acetoxymethyl-3,5-bis-benzyloxy-tetrahydro-pyran-4-yl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 80 percent / tetrabutylammonium bromide, 10 percent NaOH / CH₂Cl₂ / 18 h / Ambient temperature

2: 4.5 percent / pyridine / 48 h / Ambient temperature

3: trifluoroacetic acid / 12 h / Ambient temperature

With sodium hydroxide; tetrabutylammomium bromide; In pyridine; dichloromethane; trifluoroacetic acid;