bis{[3,5-bis(octyloxy)phenyl]methyl} 11''-(carboxymethoxy)-4'',15''-dioxo-3',3''-(methanoxymethano[1,3]benzenomethanoxymethano)-3'H,3''H-dicyclopropa[1,9:3,15][5,6]fullerene-C₆₀-I_h-3',3''-dicarboxylate

Base Information

• Chemical Name: bis{[3,5-bis(octyloxy)phenyl]methyl} 11''-(carboxymethoxy)-4'',15''-dioxo-3',3''-(methanoxymethano[1,3]benzenomethanoxymethano)-3'H,3''H-dicyclopropa[1,9:3,15][5,6]fullerene-C₆₀-I_h-3',3''-dicarboxylate
• CAS No.: 220791-20-8
• Molecular Formula: C₁₂₂H₈₈O₁₅
• Molecular Weight: 1794.03
• Mol file: 220791-20-8.mol

Synonyms:bis{[3,5-bis(octyloxy)phenyl]methyl} 11''-(carboxymethoxy)-4'',15''-dioxo-3',3''-(methanoxymethano[1,3]benzenomethanoxymethano)-3'H,3''H-dicyclopropa[1,9:3,15][5,6]fullerene-C₆₀-I_h-3',3''-dicarboxylate

Chemical Property of bis{[3,5-bis(octyloxy)phenyl]methyl} 11''-(carboxymethoxy)-4'',15''-dioxo-3',3''-(methanoxymethano[1,3]benzenomethanoxymethano)-3'H,3''H-dicyclopropa[1,9:3,15][5,6]fullerene-C₆₀-I_h-3',3''-dicarboxylate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of bis{[3,5-bis(octyloxy)phenyl]methyl} 11''-(carboxymethoxy)-4'',15''-dioxo-3',3''-(methanoxymethano[1,3]benzenomethanoxymethano)-3'H,3''H-dicyclopropa[1,9:3,15][5,6]fullerene-C₆₀-I_h-3',3''-dicarboxylate

There total 1 articles about bis{[3,5-bis(octyloxy)phenyl]methyl} 11''-(carboxymethoxy)-4'',15''-dioxo-3',3''-(methanoxymethano[1,3]benzenomethanoxymethano)-3'H,3''H-dicyclopropa[1,9:3,15][5,6]fullerene-C₆₀-I_h-3',3''-dicarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

bis{[3,5-bis(octyloxy)phenyl]methyl} 11''-[2-(1,1-dimethylethoxy)-2-oxoethoxy]-4'',15''-dioxo-3',3''-(methanoxymethano[1,3]benzenomethanoxymethano)-3'H,3''H-dicyclopropa[1,9:3,15][5,6]fullerene-C60-Ih-3',3''-dicarboxylate → bis{[3,5-bis(octyloxy)phenyl]methyl} 11''-(carboxymethoxy)-4'',15''-dioxo-3',3''-(methanoxymethano[1,3]benzenomethanoxymethano)-3'H,3''H-dicyclopropa[1,9:3,15][5,6]fullerene-C60-Ih-3',3''-dicarboxylate (220791-20-8)

Guidance literature:

With trifluoroacetic acid; In dichloromethane; at 20 ℃;

DOI:10.1016/j.tet.2005.07.126

Reference yield: 64.0%

C10H13N3O2S3 (950523-42-9) + bis{[3,5-bis(octyloxy)phenyl]methyl} 11''-(carboxymethoxy)-4'',15''-dioxo-3',3''-(methanoxymethano[1,3]benzenomethanoxymethano)-3'H,3''H-dicyclopropa[1,9:3,15][5,6]fullerene-C60-Ih-3',3''-dicarboxylate (220791-20-8) → C132H99N3O16S3

Guidance literature:

With dmap; benzotriazol-1-ol; dicyclohexyl-carbodiimide; In dichloromethane; at 20 ℃; for 24h;

DOI:10.1039/b706319a

Reference yield: 24.0%

bis{[3,5-bis(octyloxy)phenyl]methyl} 11''-(carboxymethoxy)-4'',15''-dioxo-3',3''-(methanoxymethano[1,3]benzenomethanoxymethano)-3'H,3''H-dicyclopropa[1,9:3,15][5,6]fullerene-C60-Ih-3',3''-dicarboxylate (220791-20-8) + {3,5-bis-[9-(4-dodecyloxy-phenyl)-[1,10]phenanthrolin-2-yl]-phenyl}-methanol (757248-91-2) → C189H162N4O17

Guidance literature:

With dmap; benzotriazol-1-ol; dicyclohexyl-carbodiimide; 2-methyl-but-2-ene; In dichloromethane; at 0 - 20 ℃; for 40h;

DOI:10.1016/j.tet.2005.07.126