Technology Process of potassium trifluoro(2-methylbenzoyl)borate
There total 4 articles about potassium trifluoro(2-methylbenzoyl)borate which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
9-azanoradamantane N-oxyl; acetic acid; sodium nitrite;
In
acetonitrile;
at 20 ℃;
for 18h;
Reagent/catalyst;
Solvent;
Temperature;
Catalytic behavior;
Sealed tube;
DOI:10.1002/anie.201901748
- Guidance literature:
-
1-(ethoxy(o-tolyl)methyl)-1H-benzotriazole;
With
n-butyllithium;
In
tetrahydrofuran; hexane;
Inert atmosphere;
Cooling with acetone-dry ice;
With
Trimethyl borate;
In
tetrahydrofuran; hexane;
at 20 ℃;
for 1.11667h;
Inert atmosphere;
Cooling with acetone-dry ice;
With
potassium hydrogen bifluoride; water;
In
tetrahydrofuran; hexane;
for 12h;
DOI:10.1021/ol300668m
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: sulfuric acid; orthoformic acid triethyl ester / tetrahydrofuran / 14.25 h / 20 - 70 °C
2.1: n-butyllithium / tetrahydrofuran; hexane / Inert atmosphere; Cooling with acetone-dry ice
2.2: 1.12 h / 20 °C / Inert atmosphere; Cooling with acetone-dry ice
2.3: 12 h
With
n-butyllithium; sulfuric acid; orthoformic acid triethyl ester;
In
tetrahydrofuran; hexane;
DOI:10.1021/ol300668m
![potassium trifluoro[hydroxy(o-tolyl)methyl]borate](/Databaselist/images/loading.webp)
