Technology Process of C29H44O3Si2
There total 7 articles about C29H44O3Si2 which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
at 20 ℃;
for 19h;
diastereoselective reaction;
DOI:10.1016/j.tetasy.2012.03.001
- Guidance literature:
-
Multi-step reaction with 6 steps
1.1: tetrahydrofuran / 2 h / -78 - 20 °C
1.2: Saturated solution
2.1: oxalyl dichloride; dimethyl sulfoxide / dichloromethane / 0.75 h / -78 °C
2.2: -78 - 20 °C
3.1: Grubbs catalyst first generation / dichloromethane / 20 °C
4.1: sodium tetrahydroborate; cerium(III) chloride heptahydrate / 3 h / 0 - 20 °C
5.1: 1H-imidazole / dichloromethane / 6 h / 20 °C
6.1: sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid / dichloromethane / 19 h / 20 °C
With
1H-imidazole; Grubbs catalyst first generation; sodium tetrahydroborate; oxalyl dichloride; cerium(III) chloride heptahydrate; sodium hydrogencarbonate; dimethyl sulfoxide; 3-chloro-benzenecarboperoxoic acid;
In
tetrahydrofuran; dichloromethane;
2.1: Swern oxidation / 2.2: Swern oxidation;
DOI:10.1016/j.tetasy.2012.03.001
- Guidance literature:
-
Multi-step reaction with 8 steps
1.1: dimethyl sulfoxide / 20 °C
2.1: diisobutylaluminium hydride / dichloromethane / 2 h / -78 °C
3.1: tetrahydrofuran / 2 h / -78 - 20 °C
3.2: Saturated solution
4.1: oxalyl dichloride; dimethyl sulfoxide / dichloromethane / 0.75 h / -78 °C
4.2: -78 - 20 °C
5.1: Grubbs catalyst first generation / dichloromethane / 20 °C
6.1: sodium tetrahydroborate; cerium(III) chloride heptahydrate / 3 h / 0 - 20 °C
7.1: 1H-imidazole / dichloromethane / 6 h / 20 °C
8.1: sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid / dichloromethane / 19 h / 20 °C
With
1H-imidazole; Grubbs catalyst first generation; sodium tetrahydroborate; oxalyl dichloride; cerium(III) chloride heptahydrate; diisobutylaluminium hydride; sodium hydrogencarbonate; dimethyl sulfoxide; 3-chloro-benzenecarboperoxoic acid;
In
tetrahydrofuran; dichloromethane; dimethyl sulfoxide;
4.1: Swern oxidation / 4.2: Swern oxidation;
DOI:10.1016/j.tetasy.2012.03.001
