1-azido-2-[(2,3,5,6-tetramethylphenyl)ethynyl]-4-(p-toluidino)-9,10-anthraquinone

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Chemical Name:1-azido-2-[(2,3,5,6-tetramethylphenyl)ethynyl]-4-(p-toluidino)-9,10-anthraquinone
CAS No.:1450664-43-3
Molecular Formula:C₃₃H₂₆N₄O₂
Molecular Weight:510.595
Hs Code.:

Synonyms:1-azido-2-[(2,3,5,6-tetramethylphenyl)ethynyl]-4-(p-toluidino)-9,10-anthraquinone

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Chemical Property of 1-azido-2-[(2,3,5,6-tetramethylphenyl)ethynyl]-4-(p-toluidino)-9,10-anthraquinone

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Technology Process of 1-azido-2-[(2,3,5,6-tetramethylphenyl)ethynyl]-4-(p-toluidino)-9,10-anthraquinone

There total 3 articles about 1-azido-2-[(2,3,5,6-tetramethylphenyl)ethynyl]-4-(p-toluidino)-9,10-anthraquinone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 1450664-39-7
1-amino-2-[(2,3,5,6-tetramethylphenyl)ethynyl]-4-(p-toluidino)-9,10-anthraquinone

: 1450664-43-3
1-azido-2-[(2,3,5,6-tetramethylphenyl)ethynyl]-4-(p-toluidino)-9,10-anthraquinone

Guidance literature:: 1-amino-2-[(2,3,5,6-tetramethylphenyl)ethynyl]-4-(p-toluidino)-9,10-anthraquinone; With i-propyl nitrite; In acetic acid; at 50 ℃; for 2h;

With sodium azide; In water; acetic acid; for 2h;
DOI:10.1007/s11172-012-0292-2

Reference yield:

: 233683-46-0
2-methyl-4-(2,3,5,6-tetramethylphenyl)-3-butyn-2-ol

: 1450664-43-3
1-azido-2-[(2,3,5,6-tetramethylphenyl)ethynyl]-4-(p-toluidino)-9,10-anthraquinone

Guidance literature:: Multi-step reaction with 3 steps

1.1: potassium hydroxide / toluene / 2 h / Reflux

2.1: bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine / toluene / 9 h / 75 °C / Inert atmosphere

3.1: i-propyl nitrite / acetic acid / 2 h / 50 °C

3.2: 2 h

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; i-propyl nitrite; triethylamine; potassium hydroxide; In acetic acid; toluene;
DOI:10.1007/s11172-012-0292-2

Reference yield:

: 134307-04-3
1-ethynyl-2,3,5,6-tetramethylbenzene

: 1450664-43-3
1-azido-2-[(2,3,5,6-tetramethylphenyl)ethynyl]-4-(p-toluidino)-9,10-anthraquinone

Guidance literature:: Multi-step reaction with 2 steps

1.1: bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine / toluene / 9 h / 75 °C / Inert atmosphere

2.1: i-propyl nitrite / acetic acid / 2 h / 50 °C

2.2: 2 h

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; i-propyl nitrite; triethylamine; In acetic acid; toluene;
DOI:10.1007/s11172-012-0292-2