Technology Process of C42H54O7Si
There total 11 articles about C42H54O7Si which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
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Multi-step reaction with 3 steps
1: N-ethyl-N,N-diisopropylamine / dichloromethane / -78 °C
2: osmium(VIII) oxide; water; 4-methylmorpholine N-oxide / acetone / 0 - 21 °C
3: sodium periodate / water; acetone / 1 h / 21 °C
With
sodium periodate; osmium(VIII) oxide; water; 4-methylmorpholine N-oxide; N-ethyl-N,N-diisopropylamine;
In
dichloromethane; water; acetone;
DOI:10.1016/j.tet.2011.10.024
- Guidance literature:
-
Multi-step reaction with 6 steps
1.1: titanium(IV) isopropylate; tert.-butylhydroperoxide; L-(+)-diisopropyl tartrate / decane; dichloromethane / Molecular sieve
2.1: copper(I) bromide dimethylsulfide complex / tetrahydrofuran; diethyl ether
2.2: 12 h / -30 - 0 °C
3.1: sodium hydride / tetrahydrofuran; mineral oil / 0.5 h / 21 °C
3.2: 12 h / 21 °C
4.1: N-ethyl-N,N-diisopropylamine / dichloromethane / -78 °C
5.1: osmium(VIII) oxide; water; 4-methylmorpholine N-oxide / acetone / 0 - 21 °C
6.1: sodium periodate / water; acetone / 1 h / 21 °C
With
titanium(IV) isopropylate; tert.-butylhydroperoxide; sodium periodate; osmium(VIII) oxide; copper(I) bromide dimethylsulfide complex; L-(+)-diisopropyl tartrate; water; sodium hydride; 4-methylmorpholine N-oxide; N-ethyl-N,N-diisopropylamine;
In
tetrahydrofuran; diethyl ether; decane; dichloromethane; water; acetone; mineral oil;
1.1: Sharpless epoxidation;
DOI:10.1016/j.tet.2011.10.024