2-Cyclohexen-1-one,6-(methoxymethoxy)-2-methyl-5-(1-methylethenyl)-,(5S,6R)-(9CI)

Base Information

Chemical Name:2-Cyclohexen-1-one,6-(methoxymethoxy)-2-methyl-5-(1-methylethenyl)-,(5S,6R)-(9CI)
CAS No.:785786-56-3
Molecular Formula:C12H18 O3
Molecular Weight:0
Hs Code.:
Mol file:785786-56-3.mol

Synonyms:2-Cyclohexen-1-one,6-(methoxymethoxy)-2-methyl-5-(1-methylethenyl)-,(5S,6R)-(9CI)

Suppliers and Price of 2-Cyclohexen-1-one,6-(methoxymethoxy)-2-methyl-5-(1-methylethenyl)-,(5S,6R)-(9CI)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2-Cyclohexen-1-one,6-(methoxymethoxy)-2-methyl-5-(1-methylethenyl)-,(5S,6R)-(9CI)

Chemical Property:

PSA：35.53000
LogP:2.08690

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 2-Cyclohexen-1-one,6-(methoxymethoxy)-2-methyl-5-(1-methylethenyl)-,(5S,6R)-(9CI)

There total 3 articles about 2-Cyclohexen-1-one,6-(methoxymethoxy)-2-methyl-5-(1-methylethenyl)-,(5S,6R)-(9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 785786-55-2
5-isopropenyl-6-methoxymethoxy-2-methyl-cyclohex-2-enone

: 785786-56-3
5-isopropenyl-6-methoxymethoxy-2-methylcyclohex-2-enone

Guidance literature:: 5-isopropenyl-6-methoxymethoxy-2-methyl-cyclohex-2-enone; With lithium diisopropyl amide; In tetrahydrofuran; at -78 ℃; for 1.5h; Inert atmosphere;

With water; In tetrahydrofuran; at -65 - 24 ℃; Inert atmosphere;
DOI:10.1021/jacs.0c12998

Reference yield: 84.0%

: 107-30-2
chloromethyl methyl ether

: 869162-67-4
(5S)-6-hydroxy-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enone

: 785786-55-2
5-isopropenyl-6-methoxymethoxy-2-methyl-cyclohex-2-enone

: 785786-56-3
5-isopropenyl-6-methoxymethoxy-2-methylcyclohex-2-enone

Guidance literature:: With dmap; N-ethyl-N,N-diisopropylamine; at 40 ℃; for 15h;
DOI:10.1016/j.tetlet.2004.08.041

Reference yield:

: 869162-67-4
(5S)-6-hydroxy-2-methyl-5-(prop-1-en-2-yl)cyclohex-2-enone

: 785786-56-3
5-isopropenyl-6-methoxymethoxy-2-methylcyclohex-2-enone

Guidance literature:: Multi-step reaction with 2 steps

1: 84 percent / diisopropylethylamine; DMAP / 15 h / 40 °C

2: 69 percent / LDA / tetrahydrofuran / 0.5 h / -78 °C

With dmap; N-ethyl-N,N-diisopropylamine; lithium diisopropyl amide; In tetrahydrofuran;
DOI:10.1016/j.tetlet.2004.08.041