C₂₉H₄₇NP₂S₂

Base Information

• Chemical Name: C₂₉H₄₇NP₂S₂
• CAS No.: 1616367-32-8
• Molecular Formula: C₂₉H₄₇NP₂S₂
• Molecular Weight: 535.778
• Mol file: 1616367-32-8.mol

Synonyms:C₂₉H₄₇NP₂S₂

Chemical Property of C₂₉H₄₇NP₂S₂

Chemical Property:

Purity/Quality:

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Technology Process of C₂₉H₄₇NP₂S₂

There total 4 articles about C₂₉H₄₇NP₂S₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

bromobenzene (108-86-1,52753-63-6) + C29H54BNO2P2S2 (1616367-31-7) → C29H47NP2S2 (1616367-32-8)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate; In toluene; at 90 ℃; for 48h; Inert atmosphere;

DOI:10.1021/ja5044243

Reference yield:

C23H43NP2S2 (1616367-30-6) → C29H47NP2S2 (1616367-32-8)

Guidance literature:

Multi-step reaction with 2 steps

1: (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; 4,4'-di-tert-butyl-2,2'-bipyridine / tetrahydrofuran / 21 h / 90 °C / Inert atmosphere

2: tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate / toluene / 48 h / 90 °C / Inert atmosphere

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; potassium carbonate; 4,4'-di-tert-butyl-2,2'-bipyridine; In tetrahydrofuran; toluene;

DOI:10.1021/ja5044243

Reference yield:

2,6-dimethylpyridine (108-48-5) → C29H47NP2S2 (1616367-32-8)

Guidance literature:

Multi-step reaction with 3 steps

1.1: N,N,N,N,-tetramethylethylenediamine; n-butyllithium / diethyl ether; hexane / 4 h / 0 °C / Inert atmosphere

1.2: 15 h / -78 - 20 °C / Inert atmosphere

1.3: 4 h / 0 - 20 °C / Inert atmosphere

2.1: (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; 4,4'-di-tert-butyl-2,2'-bipyridine / tetrahydrofuran / 21 h / 90 °C / Inert atmosphere

3.1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate / toluene / 48 h / 90 °C / Inert atmosphere

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; n-butyllithium; (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; N,N,N,N,-tetramethylethylenediamine; potassium carbonate; 4,4'-di-tert-butyl-2,2'-bipyridine; In tetrahydrofuran; diethyl ether; hexane; toluene;

DOI:10.1021/ja5044243

upstream raw materials:

2,6-dimethylpyridine

bromobenzene

C₂₉H₅₄BNO₂P₂S₂

di(tert-butyl)chlorophosphine

Downstream raw materials:

C₂₉H₄₇NP₂