(R,E)-hex-4-en-3-ylbenzene

Base Information

Chemical Name:(R,E)-hex-4-en-3-ylbenzene
CAS No.:78087-00-0
Molecular Formula:C₁₂H₁₆
Molecular Weight:160.259
Hs Code.:

Synonyms:(R,E)-hex-4-en-3-ylbenzene

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Chemical Property of (R,E)-hex-4-en-3-ylbenzene

Chemical Property:

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Technology Process of (R,E)-hex-4-en-3-ylbenzene

There total 3 articles about (R,E)-hex-4-en-3-ylbenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 38.0%

: 63537-05-3,91861-50-6
(E)-(3-chlorobut-1-en-1-yl)benzene

: 925-90-6
ethylmagnesium bromide

: 15325-63-0
(E)-3-methyl-1-phenyl-1-pentene

: 78087-01-1
(S,E)-hex-4-en-3-ylbenzene

: 78086-99-4
(R,Z)-hex-4-en-3-ylbenzene

: 78087-00-0
(R,E)-hex-4-en-3-ylbenzene

Guidance literature:: (E)-(3-chlorobut-1-en-1-yl)benzene; With copper(I) thiophene-2-carboxylate; O,O’-(R)-1,1’-(dinaphthyl-2,2’-diyl)-N,N’-di-(R,R)-1-(2-methoxyphenyl)ethylphosphoramidite; In dichloromethane; at -78 ℃; for 0.166667h; Inert atmosphere;

ethylmagnesium bromide; In diethyl ether; dichloromethane; at -78 ℃; for 1.5h; optical yield given as %ee; enantioselective reaction; Inert atmosphere;
DOI:10.1002/anie.201005373

Reference yield:

: 20068-21-7
(R)-4-Phenyl-1-hexene

: 78086-99-4
(R,Z)-hex-4-en-3-ylbenzene

: 78087-00-0
(R,E)-hex-4-en-3-ylbenzene

Guidance literature:: [nickel(II)bis(N-methylsalicylideneiminate)]; triisobutylaluminum; at 25 ℃; for 1h;
DOI:10.1021/jo00331a025

Reference yield:

: 1896-62-4
(E)-benzalacetone

: 15325-63-0
(E)-3-methyl-1-phenyl-1-pentene

: 78087-01-1
(S,E)-hex-4-en-3-ylbenzene

: 78086-99-4
(R,Z)-hex-4-en-3-ylbenzene

: 78087-00-0
(R,E)-hex-4-en-3-ylbenzene

Guidance literature:: Multi-step reaction with 3 steps

1.1: lithium aluminium tetrahydride / diethyl ether / 0.67 h / 0 °C / Inert atmosphere

2.1: acetyl chloride / ethanol / 2 h / 20 °C / Inert atmosphere

3.1: copper(I) thiophene-2-carboxylate; O,O’-(R)-1,1’-(dinaphthyl-2,2’-diyl)-N,N’-di-(R,R)-1-(2-methoxyphenyl)ethylphosphoramidite / dichloromethane / 0.17 h / -78 °C / Inert atmosphere

3.2: 1.5 h / -78 °C / Inert atmosphere

With lithium aluminium tetrahydride; copper(I) thiophene-2-carboxylate; O,O’-(R)-1,1’-(dinaphthyl-2,2’-diyl)-N,N’-di-(R,R)-1-(2-methoxyphenyl)ethylphosphoramidite; acetyl chloride; In diethyl ether; ethanol; dichloromethane;
DOI:10.1002/anie.201005373