phenylmethyl [(1S)-3-diazo-1-ethyl-2-oxopropyl]carbamate

Base Information

Chemical Name:phenylmethyl [(1S)-3-diazo-1-ethyl-2-oxopropyl]carbamate
CAS No.:922705-22-4
Molecular Formula:C₁₃H₁₅N₃O₃
Molecular Weight:261.28
Hs Code.:

Synonyms:phenylmethyl [(1S)-3-diazo-1-ethyl-2-oxopropyl]carbamate

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Chemical Property of phenylmethyl [(1S)-3-diazo-1-ethyl-2-oxopropyl]carbamate

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Technology Process of phenylmethyl [(1S)-3-diazo-1-ethyl-2-oxopropyl]carbamate

There total 1 articles about phenylmethyl [(1S)-3-diazo-1-ethyl-2-oxopropyl]carbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 186581-53-3,908094-01-9,334-88-3
diazomethane

: 42918-86-5,1145-79-5,2900-20-1,20395-87-3
(S)-2-(((benzyloxy)carbonyl)amino)butanoic acid

: 922705-22-4
phenylmethyl [(1S)-3-diazo-1-ethyl-2-oxopropyl]carbamate

Guidance literature:: (S)-2-(((benzyloxy)carbonyl)amino)butanoic acid; With 4-methyl-morpholine; chloroformic acid ethyl ester; In tetrahydrofuran; at -15 ℃; for 0.25h;

diazomethane; In tetrahydrofuran; dichloromethane; at -15 - 20 ℃;
DOI:10.1002/hlca.200690235

Reference yield: 87.0%

: 922705-22-4
phenylmethyl [(1S)-3-diazo-1-ethyl-2-oxopropyl]carbamate

: 271600-24-9
(3S)-3-({[(phenylmethyl)oxy]carbonyl}amino)pentanoic acid

Guidance literature:: silver trifluoroacetate; In 1,4-dioxane; water; for 0.5h; sonication;
DOI:10.1002/hlca.200690235

Reference yield:

: 922705-22-4
phenylmethyl [(1S)-3-diazo-1-ethyl-2-oxopropyl]carbamate

: 922705-43-9
(3S)-3-(methyl{[(phenylmethyl)oxy]carbonyl}amino)pentanoic acid

Guidance literature:: Multi-step reaction with 3 steps

1: 87 percent / CF₃COOAg / dioxane; H₂O / 0.5 h / sonication

2: 35 percent / CSA; AcOH / toluene / 90 °C

3: 50 percent / Et₃SiH; CF₃COOH / CH₂Cl₂

With triethylsilane; trifluoroacetic acid; camphor-10-sulfonic acid; silver trifluoroacetate; acetic acid; In 1,4-dioxane; dichloromethane; water; toluene; 1: Wolff rearrangement;
DOI:10.1002/hlca.200690235